《Highly Productive α-Alkylation of Ketones with Alcohols Mediated by an Ir-Oxalamidato/Solid Base Catalyst System》 was published in Organic Process Research & Development in 2020. These research results belong to Shimizu, Hideo; Maeda, Hironori; Nara, Hideki. Recommanded Product: 5-Hexen-1-ol The article mentions the following:
An Ir-oxalamidato complexes I [R = Ph, 2-MeC6H4, 2-Me-4-OH-5-t-BuC6H2, etc.] were synthesized and examined for their catalytic activity in the synthesis of alkylated ketones R1C(O)R2 [R1 = Me, n-hexyl, CH2CH2C6H5, etc.; R2 = n-hexyl, CH2CH2C6H5, 4-OMeC6H4CH2CH2, etc.]. Synthesized Ir-oxalamidato complex I [R = 2-Me-4-OH-5-t-BuC6H2] in combination with a solid base (e.g., magnesium aluminometasilicate/Ca(OH)2) significantly improved the catalyst productivity in α-alkylation of Me ketones with primary alcs. Optimization through systematic variation of the oxalamidato ligand led to a practical turnover number (TON) of 10 000-40 000. In the experimental materials used by the author, we found 5-Hexen-1-ol(cas: 821-41-0Recommanded Product: 5-Hexen-1-ol)
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Recommanded Product: 5-Hexen-1-ol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts