Giofre, Sabrina; Molteni, Letizia; Nava, Donatella; Lo Presti, Leonardo; Beccalli, Egle Maria published an article in 2021. The article was titled 《Enantio- and Regioselective Palladium(II)-Catalyzed Dioxygenation of (Aza-)Alkenols》, and you may find the article in Angewandte Chemie, International Edition.Category: alcohols-buliding-blocks The information in the text is summarized as follows:
An oxidative Pd-catalyzed intra-intermol. dioxygenation of (aza-)alkenols were reported, with total regioselectivity. To study the stereoselectivity, different chiral ligands as well as different hypervalent-iodine compounds was compared. In particular, by using a C-6 modified pyridinyl-oxazoline (Pyox) ligand and hypervalent iodine bearing an aromatic ring, an excellent enantio- and diastereoselectivity was achieved. In the experiment, the researchers used many compounds, for example, 5-Hexen-1-ol(cas: 821-41-0Category: alcohols-buliding-blocks)
5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Category: alcohols-buliding-blocks
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts