Ghadermazi, Mohammad; Molaei, Somayeh; Ghadermazi, Nahid published the artcile< Introduction of Fe into mesoporous MCM-41 for the synthesis of 5-substituted 1H-Tetrazoles from aryl nitriles in water>, Recommanded Product: 2-(Phenylthio)ethanol, the main research area is mesoporous supported iron silica catalyst preparation; tetrazole sulfoxide preparation green chem; aryl nitrile sulfide oxidation water.
In this exploration, new recyclable mesoporous-supported iron particles with the ligand and without ligand (MCM-41@ 3,4,5-tri hydroxyphenyl acetic acid @Fe and MCM-41@Fe) have been developed through post-functionalization modification of silica MCM-41. These catalysts were demonstrated to be novel, effective, and green for the synthesis of 5-substituted 1H-tetrazoles from aryl nitriles in water. In these systems, 5-substituted 1H-tetrazoles are produced as the only product. Fe3+ species were identified as active sites. The ordered mesoporous iron-silica catalyst with the ligand displayed better catalytic activity compared to iron-silica catalyst without the ligand, which was ascribed to the improvement of the inter-action of iron with the support. The catalysts can be easily separated using simple recovery and reused several times with consistent activity.
Microporous and Mesoporous Materials published new progress about Aromatic nitriles Role: RCT (Reactant), RACT (Reactant or Reagent). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Recommanded Product: 2-(Phenylthio)ethanol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts