C-H and C-S Bond Cleavage in Uranium(III) Thiolato Complexes was written by Arliguie, Therese;Lescop, Christophe;Ventelon, Lionel;Leverd, Pascal C.;Thuery, Pierre;Nierlich, Martine;Ephritikhine, Michel. And the article was included in Organometallics in 2001.Electric Literature of C4H9NaS This article mentions the following:
Reduction of the uranium(IV) thiolates Cp*2U(SR)2 (Cp* = η-C5Me5, R = Ph, Me, iPr or tBu) with sodium amalgam afforded the corresponding U(III) complexes Na[Cp*2U(SR)2] (R = Ph, 2a; Me, 2b; iPr, 2c) or the U(IV) sulfide Na[Cp*2U(StBu)(S)]. C-S bond cleavage of a thiolate ligand was also observed during the thermal decomposition of 2c into the sulfide Na[Cp*2U(SiPr)(S)], whereas 2b was transformed in refluxing THF into the thiametallacyclopropane complex Na[Cp*2U(SMe)(SCH2)], resulting from C-H bond activation of a SMe group. The x-ray crystal structures of [Na(18-crown-6)(THF)2][Cp*2U(SiPr)2], [Na(18-crown-6)][Cp*2U(StBu)(S)], and [Na(18-crown-6)(THF)2][Cp*2U(SMe)(SCH2)] have been determined In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2Electric Literature of C4H9NaS).
Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Electric Literature of C4H9NaS
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts