Syntheses of hydrido selenophenolato iron(II) complexes and their catalytic application in hydrosilylation of aldehydes and ketones was written by Wang, Yangyang;Ren, Shishuai;Zhang, Wenbo;Xue, Benjing;Qi, Xinghao;Sun, Hongjian;Li, Xiaoyan;Fuhr, Olaf;Fenske, Dieter. And the article was included in Catalysis Communications in 2018.SDS of cas: 1777-82-8 This article mentions the following:
Three novel selenophenolato hydrido iron(II) complexes [cis-(H)(SeAr)Fe(PMe3)4] (Ar = C6H5 (I), p-MeOC6H4 (II) and o-MeC6H4 (III)) were prepared through the reaction of Fe(PMe3)4 with selenophenols ArSeH via Se-H activation. The iron hydrido complexes I, II and III could catalyze the hydrosilylation of aldehydes and ketones. Among them complex II is the best catalyst for this process. Furthermore, α,β-unsaturated alcs. could be obtained from the selective reduction reactions of the corresponding α,β-unsaturated carbonyls catalyzed by hydrido iron(II) complex II. This catalytic system has good tolerance for some common groups but it is easy to reduce the nitro group to an amino group. The experiments indicate that the chemoselectivity for this catalytic system is -CHO > -NO2 > -C(:O)CH3. The crystal structure of III was determined by X-ray diffraction. In the experiment, the researchers used many compounds, for example, (2,4-Dichlorophenyl)methanol (cas: 1777-82-8SDS of cas: 1777-82-8).
(2,4-Dichlorophenyl)methanol (cas: 1777-82-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.SDS of cas: 1777-82-8
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts