Self-assembled nanoporphyrins in the presence of gold bio-nanoparticles as heterogeneous nano-biocatalyst for green production of aldehydes and ketones was written by Taheri Bazmi, Mahmoud;Naeimi, Atena;Saeednia, Samira;Hatefi Ardakani, Mehdi. And the article was included in Applied Organometallic Chemistry in 2020.Recommanded Product: 1777-82-8 This article mentions the following:
A simple and facile self-assembly method for the successful fabrication of a biol. macromol., MnTPPCl (manganese(III) chloride 5,10,15,20-tetraphenylporphyrin), intercalated into gold nanoparticles using the cooperative effects of Sesbania sesban plant was reported. This biohybrid was characterized by using various techniques for further investigation. The catalytic activity of this biol. hybrid was considered in the production of aldehydes RCHO (R = Ph, furan-2-yl, 2-phenylethenyl, etc.) and ketones RC(O)R1 (R = Ph; R1 = Me, Et) from primary RCH2OH and secondary alcs., RCH(OH)R1 resp. Excellent conversions and selectivities were obtained applying Au@MnTPPCl colloidal nanocomposite and NaIO4 as an oxygen donor in ethanol. In the experiment, the researchers used many compounds, for example, (2,4-Dichlorophenyl)methanol (cas: 1777-82-8Recommanded Product: 1777-82-8).
(2,4-Dichlorophenyl)methanol (cas: 1777-82-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Recommanded Product: 1777-82-8
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts