Poptic, Anna L. et al. published their research in Inorganic Chemistry in 2021 | CAS: 29364-29-2

Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.COA of Formula: C4H9NaS

Iron(II/III) Halide Complexes Promote the Interconversion of Nitric Oxide and S-Nitrosothiols through Reversible Fe-S Interaction was written by Poptic, Anna L.;Zhang, Shiyu. And the article was included in Inorganic Chemistry in 2021.COA of Formula: C4H9NaS This article mentions the following:

Heme and non-heme iron in biol. mediate the storage/release of NO• from S-nitrosothiols as a means to control the biol. concentration of NO•. Despite their importance in many physiol. processes, the mechanisms of N-S bond formation/cleavage at Fe centers have been controversial. Herein, authors report the interconversion of NO• and S-nitrosothiols mediated by FeII/FeIII chloride complexes. The reaction of 2 equivalent of S-nitrosothiol (Ph3CSNO) with [Cl6FeII2]2- results in facile release of NO• and formation of iron(III) halothiolate. Detailed spectroscopic studies, including in situ UV-vis, IR, and Moessbauer spectroscopy, support the interaction of the S atom with the FeII center. This is in contrast to the proposed mechanism of NO• release from the well-studied “red product” κ1-N bound S-nitrosothiol FeII complex, [(CN)5Fe(κ1-N-RSNO)]3-. Addnl., FeIII chloride can mediate NO• storage through the formation of S-nitrosothiols. Treatment of iron(III) halothiolate with 2 equivalent of NO• regenerates Ph3CSNO with the FeII source trapped as the S = 3/2 {FeNO}7 species [Cl3FeNO]–, which is inert toward further coordination and activation of S-nitrosothiols. Their work demonstrates how labile iron can mediate the interconversion of NO•/thiolate and S-nitrosothiol, which has important implications toward how Nature manages the biol. concentration of free NO•. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2COA of Formula: C4H9NaS).

Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.COA of Formula: C4H9NaS

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts