Efficient splitting of alcohols into hydrogen and C-C coupled products over ultrathin Ni-doped ZnIn2S4 nanosheet photocatalyst was written by Li, Jing-Yu;Qi, Ming-Yu;Xu, Yi-Jun. And the article was included in Chinese Journal of Catalysis in 2022.Name: (4-Chlorophenyl)methanol This article mentions the following:
Integrating selective organic synthesis with hydrogen (H2) evolution in one photocatalytic redox reaction system sheds light on the underlying approach for concurrent employment of photogenerated electrons and holes towards efficient production of solar fuels and chems. In this work, a facile one-pot oil bath method has been proposed to fabricate a noble metal-free ultrathin Ni-doped ZnIn2S4 (ZIS/Ni) composite nanosheet for effective solar-driven selective dehydrocoupling of benzyl alc. into value-added C-C coupled hydrobenzoin and H2 fuel, which exhibits higher performance than pure ZIS nanosheet. The remarkably improved photoredox activity of ZIS/Ni is mainly attributed to the optimized electron structure featuring narrower band gap and suitable energy band position, which facilitates the ability of light harvesting and photoexcited charge carrier separation and transfer. Furthermore, it has been demonstrated that it is feasible to employ ZIS/Ni for various aromatic alcs. dehydrocoupling to the corresponding C-C coupled products. It is expected that this work can stimulate further interest on the establishment of innovative photocatalytic redox platform coupling clean solar fuels synthesis and selective organic conversion in a sustainable manner. In the experiment, the researchers used many compounds, for example, (4-Chlorophenyl)methanol (cas: 873-76-7Name: (4-Chlorophenyl)methanol).
(4-Chlorophenyl)methanol (cas: 873-76-7) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Name: (4-Chlorophenyl)methanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts