Comparative study on nucleophilic/electrophilic behaviour of divalent organosulfur compounds: a DFT study was written by Ahmed, Nizamuddin;Bhattacharjee, Saibal Kanti;Bhattacharyya, Pradip Kr.. And the article was included in Journal of the Indian Chemical Society in 2014.Related Products of 29364-29-2 This article mentions the following:
Electrophilic/nucleophilic behavior of twenty-five bivalent organosulfur compounds were studied using global and local DFT based reactivity descriptors at B3LYP/6-311++G(d,p) and MP2/6-311++G(d,p) levels of theory. Global reactivity descriptors are used to observe overall stability of the compounds and local parameters are used to quantify reactivity of the sulfur center. Further we have observed the effect of solvents, ethanol and water on the reactivity pattern. Gibbs free energy of solvation is used to measure stability of the compounds in solvent phases. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2Related Products of 29364-29-2).
Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Related Products of 29364-29-2
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts