Dehydrogenative Esterification and Dehydrative Etherification by Coupling of Primary Alcohols Based on Catalytic Function Switching of an Iridium Complex was written by Onoda, Mitsuki;Fujita, Ken-ichi. And the article was included in ChemistrySelect in 2022.Name: (4-Chlorophenyl)methanol This article mentions the following:
In this study, a new catalytic function switching system: not only dehydrogenative esterification but also dehydrative etherification under environmentally friendly conditions were accomplished by the employment of a single iridium catalyst based on catalytic function switching was successfully developed. Using benzyl alc. as a starting material, the esterification product, benzyl benzoate, and the etherification product, dibenzyl ether, were obtained in 92% and 89% yields, resp., by employing same iridium catalyst precursor bearing a dihydroxybipyridine ligand, under optimized conditions. In the experiment, the researchers used many compounds, for example, (4-Chlorophenyl)methanol (cas: 873-76-7Name: (4-Chlorophenyl)methanol).
(4-Chlorophenyl)methanol (cas: 873-76-7) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Name: (4-Chlorophenyl)methanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts