(2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal hydrate (cas: 10030-85-0) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Name: (2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal hydrate
Analyzing and assigning carbon-13 chemical shift tensors in α-L-rhamnose monohydrate single crystals was written by Liu, Fang;Phung, Cu G.;Alderman, D. W.;Grant, David M.. And the article was included in Journal of Magnetic Resonance, Series A in 1996.Name: (2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal hydrate This article mentions the following:
The carbon-13 chem.-shift tensors of α-L-rhamnose (6-deoxy-L-mannose) monohydrate (C8H12O5·H2O [10030-85-0]) are measured using two-dimensional chem.-shift correlation spectroscopy. The tensors and the orientation of the 2-fold axis along the b crystallog. axis in the sample frame were obtained by symmetry-constrained fitting of the data. Ab initio gauge invariant AO computations of the chem. shielding are then used to assign the tensors to the carbons in the rhamnose mol. and to the two mols. in the unit cell. These computations are also used to find the direction of the b crystallog. axis along the 2-fold axis and to make initial estimates of the a and c crystallog. axes in the sample. The final a and c crystallog. axes are then determined with a 2-dimensional dipolar spectrum. A 2nd independent method, 1-dimensional spectra taken with the applied field along directions perpendicular to the (011), the (110), and the (100) crystallog. planes, was used to confirm the result. In the experiment, the researchers used many compounds, for example, (2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal hydrate (cas: 10030-85-0Name: (2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal hydrate).
(2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal hydrate (cas: 10030-85-0) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Name: (2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal hydrate
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts