Mixed diboration of alkenes in a metal-free context was written by Miralles, Nuria;Cid, Jessica;Cuenca, Ana B.;Carbo, Jorge J.;Fernandez, Elena. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2015.Reference of 1214264-88-6 This article mentions the following:
Exptl. and theor. rationalization on regioselective mixed diboration of alkenes, with the unsym. diboron reagent Bpin-Bdan (pin = pinacolate, dan = 1,8-diaminonaphthalene) , providing the protecting Bdan moiety in the internal position. E.g., reaction of PhCH:CH2 with Bpin-Bdan in MeOH in the presence of Cs2CO3 at 70° gave 40% isolated yield of PhCH(Bdan)CH2Bpin. Calculation on the energy profile for the organocatalytic diboration of propene with Bpin-Bdan diboron reagent is reported. In the experiment, the researchers used many compounds, for example, 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine (cas: 1214264-88-6Reference of 1214264-88-6).
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine (cas: 1214264-88-6) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Reference of 1214264-88-6
Referemce:
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Alcohols – Chemistry LibreTexts