Palladium-catalyzed intermolecular transthioetherification of aryl halides with thioethers and thioesters was written by Li, Yahui;Bao, Gao;Wu, Xiao-Feng. And the article was included in Chemical Science in 2020.Recommanded Product: 68716-49-4 This article mentions the following:
A new palladium-catalyzed intermol. transthioetherification reaction of aryl halides with thioethers and thioesters was developed. The synthetic utility and practicality of this catalytic protocol were demonstrated in a wide range of successful transformations (>70 examples). This catalytic protocol was applicable in carbonylative coupling processes as well, and the first example of carbonylative methylthioesterification of aryl halides was achieved. Notably, this work also provided an approach to using natural products, such as methionine and selenomethionine, as the functional group sources. In the experiment, the researchers used many compounds, for example, 2-(4-Bromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (cas: 68716-49-4Recommanded Product: 68716-49-4).
2-(4-Bromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (cas: 68716-49-4) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Recommanded Product: 68716-49-4
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts