Green synthesis of nitriles using non-noble metal oxides-based nanocatalysts was written by Jagadeesh, Rajenahally V.;Junge, Henrik;Beller, Matthias. And the article was included in Nature Communications in 2014.Product Details of 220227-37-2 This article mentions the following:
An environmentally benign chemoselective synthesis of structurally diverse aryl, heterocyclic, allylic and aliphatic nitriles from easily available alcs. applying aqueous ammonia and mol. oxygen was described. Key to success for this synthesis was the use of nitrogen-doped graphene-layered non-noble metal oxides as stable and durable nanocatalysts. As an example a renewable synthesis of adiponitrile, an industrially important bulk chem. was reported. In the experiment, the researchers used many compounds, for example, (3,4,5-Trifluorophenyl)methanol (cas: 220227-37-2Product Details of 220227-37-2).
(3,4,5-Trifluorophenyl)methanol (cas: 220227-37-2) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Product Details of 220227-37-2
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts