Synthesis, structure and reactivity in styrene polymerization by heterocyclic alkoxy- and thiolatotitanium(IV) complexes was written by Aragon, Pedro J.;Carrillo-Hermosilla, Fernando;Villasenor, Elena;Otero, Antonio;Antinolo, Antonio;Rodriguez, Ana M.. And the article was included in European Journal of Inorganic Chemistry in 2006.COA of Formula: C7H9NO This article mentions the following:
The reaction of [Ti(OiPr)4] or [TiCl4(THF)2] with two equivalent of pyridyl alcs. or pyridyl or pyrimidinyl thiols has proven to be a good preparative method to obtain a variety of non-metallocene diisopropoxo- or dichlorotitanium(IV) complexes. The complexes [Ti(X)2{2-(OCH2)-6-R-(C5H3N)}2] were found to be dynamic at room temperature, with the heterocyclic alkoxy ligand dissociating and recoordinating in a κ2-N,O chelate fashion, as revealed by a single-crystal X-ray anal. of [Ti(OiPr)2{2-(OCH2)(C5H4N)}2] (1). The dynamic behavior of some of the resulting thiolato complexes was also studied and the single-crystal X-ray anal. of [Ti(OiPr)2{2-S-4,6-Me2-(C4HN2)}2] (5) revealed a κ2-N,S system for these complexes. These complexes show catalytic activity in the polymerization of styrene upon activation with methylaluminoxane. In the experiment, the researchers used many compounds, for example, 6-Methyl-2-pyridinemethanol (cas: 1122-71-0COA of Formula: C7H9NO).
6-Methyl-2-pyridinemethanol (cas: 1122-71-0) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.COA of Formula: C7H9NO
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts