Wei, Xiu-Zhi et al. published their research in Journal of Colloid and Interface Science in 2023 | CAS: 873-76-7

(4-Chlorophenyl)methanol (cas: 873-76-7) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Category: alcohols-buliding-blocks

Highly selective photocatalytic oxidation of alcohols under the application of novel metal organic frameworks (MOFs) based catalytic system was written by Wei, Xiu-Zhi;Wondu Dagnaw, Fentahun;Liu, Jianguo;Ma, Longlong. And the article was included in Journal of Colloid and Interface Science in 2023.Category: alcohols-buliding-blocks This article mentions the following:

Carboxylic acid is one of the most crucial and widely used organic chems. in daily human life activities. Hence preparation of this important chem. was performed under the application of the highly selective photo-catalysts through oxidation of alcs. to carboxylic acids. Herein, we have designed and disclosed a binary NH2-MIL-125(Ti)/ NaBr) catalyst system to realize the effective transformation of alcs. into carboxylic acids under visible light irradiation Hence, derivatives of benzyl alc. containing either electron withdrawing and donating groups as well as aliphatic primary alcs. were effectively converted into the corresponding carboxylic acids. Based on our findings, NH2-MIL-125(Ti) based photocatalytic system has shown efficient and highly selective activities for oxidation of alc. especially the in-situ conversion of co-catalyst NaBr into the corresponding free radical can enhance the alc. oxidation performance of the catalytic system. In the experiment, the researchers used many compounds, for example, (4-Chlorophenyl)methanol (cas: 873-76-7Category: alcohols-buliding-blocks).

(4-Chlorophenyl)methanol (cas: 873-76-7) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts