A recipe for new organometallic polymers and oligomers? Synthesis and structure of an oligo- and a polymeric arrangement of P-S anions was written by Rothenberger, Alexander;Shafaei-Fallah, Maryam;Shi, Weifeng. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2007.HPLC of Formula: 29364-29-2 This article mentions the following:
A route to organometallic polymers and oligomers is described using metal complexes with P/S-ligands as examples. When Davy’s reagent is suspended in THF and reacted with silver thiolates in the presence of the dppe (dppe = 1,2-bis(diphenylphosphino)ethane), a clear solution is obtained. Within 3 wk, colorless crystals [Ag24(PS4)(iPrSPS3)4{S(tol)}12(dppe)6](SiPr) (1; tol = 4-methylphenyl) were formed. Another attempt was made to generate P/S anions. When the filtrate of a reaction of P2S5 and NaStBu was layered with hexane, crystals of the 2D-polymer [Na2(S3PStBu)(dme)]n (2; dme = 1,2-dimethoxymethane) were obtained. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2HPLC of Formula: 29364-29-2).
Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.HPLC of Formula: 29364-29-2
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts