Satoh, Yasushi’s team published research in ACS Catalysis in 7 | CAS: 17877-23-5

ACS Catalysis published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Computed Properties of 17877-23-5.

Satoh, Yasushi published the artcileHighly selective synthesis of hydrosiloxanes by Au-catalyzed dehydrogenative cross-coupling reaction of silanols with hydrosilanes, Computed Properties of 17877-23-5, the publication is ACS Catalysis (2017), 7(3), 1836-1840, database is CAplus.

We report a highly selective synthesis of siloxane building blocks containing SiH2or SiH functionalities. The system AuCl(PPh3)/PPh3 or AuCl(PPh3)/PBu3 catalyzed the reaction of trihydrosilanes with silanols giving SiH2-containing siloxanes exclusively. On the other hand, a highly selective reaction of dihydrosilanes with silanols to afford SiH-containing siloxanes was achieved by simply changing the phosphine ligand to a bidentate one, xantphos. Usefulness of SiH2-containing siloxanes was demonstrated by the synthesis of a trisiloxane, Et3SiOSi(Ph)(H)OSitBuMe2, and a pentasiloxane, Ph2Si(OSiHPhOSiEt3)2, bearing SiH functionalities.

ACS Catalysis published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Computed Properties of 17877-23-5.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts