N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols was written by Nagata, Tatsuki;Okada, Kanji;Kondo, Ryota;Toyao, Takashi;Shimizu, Ken-ichi;Suzuki, Takeyuki;Obora, Yasushi. And the article was included in RSC Advances in 2022.Formula: C10H22O The following contents are mentioned in the article:
N,N-Dimethylformamide-stabilized Ru nanoparticles (NPs) provided a highly efficient catalyst for the Guerbet reaction of primary alcs. DMF-modified Ru NPs were synthesized, and characterized by transition electron microscopy, and X-ray absorption spectroscopy, XPS, and Fourier-transform IR spectroscopy. The Ru NP catalyst was highly durable during catalytic reactions under external additive/solvent-free conditions. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Formula: C10H22O).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Formula: C10H22O
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts