Hydrogenation of Citral on Pt/SiO2 Catalysts: Effect of Sn Addition and Type of Solvent was written by Barrales-Cortes, C. A.;Perez-Pastenes, H.;Pina-Victoria, J. C.;Viveros-Garcia, T.. And the article was included in Topics in Catalysis in 2020.Reference of 106-21-8 The following contents are mentioned in the article:
This work deals with the liquid-phase hydrogenation of citral over Pt monometallic and PtSn bimetallic catalysts supported on com. silica. Bimetallic catalysts contain different Sn/Pt molar ratio of 0.5, 1.0 and 1.5. Cyclohexane or 2-propanol were used as solvent. The catalysts were characterized by N2-physisorption, XRD, NH3-TPD, H2-chemisorption, and TPR. Both XRD and TPR results showed the formation of PtSn and Pt3Sn. The proportion of Pt-Sn alloys was related to the Sn/Pt molar ratio: the greater the Sn/Pt molar ratio, the greater the amount of PtSn alloy species. The amount of these species was related to the catalytic activity and selectivity in the hydrogenation of citral. Pt monometallic catalysts showed a high initial catalytic activity with high selectivity to citronellal. Bimetallic catalysts exhibited high activity and selectivity to unsaturated alcs. as geraniol and nerol. With cyclohexane as solvent, a greater amount of Pt3Sn species promote consecutive hydrogenations, and with a greater amount of PtSn alloy the formation of compounds related to cyclization of citronellal was observed The results showed that using a balanced amount of species (Pt3Sn and PtSn) and 2-propanol as solvent, a synergic effect that promotes high activity and selectivity to geraniol and nerol was observed maintaining the same levels of selectivity along reaction time. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Reference of 106-21-8).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Reference of 106-21-8
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts