ãMetal-Free Visible Light Hydroperfluoroalkylation of Unactivated Alkenes Using Perfluoroalkyl Bromidesã?was written by Yajima, Tomoko; Shigenaga, Satsuki. Electric Literature of C6H12OThis research focused onunactivated alkene perfluoroalkyl bromide hydroperfluoroalkylation visible light organocatalyst; perfluoroalkyl alkane preparation; visible light hydroperfluoroalkylation promoter; organic dye hydroperfluoroalkylation organocatalyst. The article conveys some information:
Organic dye-catalyzed visible light induced hydroperfluoroalkylation of unactivated alkenes is described. Hydroperfluoroalkylation proceeds selectively and is applicable for various perfluoroalkyl bromide and alkenes including internal alkenes. The reaction mechanism is discussed, and it is shown that the hydrogen source varies with reaction conditions. In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Electric Literature of C6H12O)
5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Electric Literature of C6H12O
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