《Mass spectrometry distinguishing C=C location and cis/trans isomers: A strategy initiated by water radical cations》 was written by Zhang, Xiaoping; Ren, Xiang; Chingin, Konstantin; Xu, Jiaquan; Yan, Xin; Chen, Huanwen. Computed Properties of C6H12O And the article was included in Analytica Chimica Acta in 2020. The article conveys some information:
We present an approach for the elucidation of C=C bond position and cis/trans isomers, which is achieved by the reaction of ambient water radical cations and double bonds, followed by the fragmentation of epoxide radical cations to generate diagnostic ions in tandem mass spectrometry. Hexenol double bond positional isomers and cis/trans isomers which exhibit different properties and biol. functions are characterized as a proof of concept. The merits of the approach include the simplicity of exptl. setup, rapid derivatization (within seconds), the obviation of organic solvents, as well as easy spectral interpretation. In the experimental materials used by the author, we found 5-Hexen-1-ol(cas: 821-41-0Computed Properties of C6H12O)
5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Computed Properties of C6H12O
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