《Cobalt-Catalyzed Acceptorless Dehydrogenation of Alcohols to Carboxylate Salts and Hydrogen》 was published in Organic Letters in 2020. These research results belong to Pradhan, Deepak Ranjan; Pattanaik, Sandip; Kishore, Jugal; Gunanathan, Chidambaram. Recommanded Product: 2,6-Pyridinedimethanol The article mentions the following:
The facile oxidation of alcs. to carboxylate salts and H2 is achieved using a simple and readily accessible cobalt pincer catalyst (NNNHtBuCoBr2). The reaction follows an acceptorless dehydrogenation pathway and displays good functional group tolerance. The amine-amide metal-ligand cooperation in cobalt catalyst is suggested to facilitate this transformation. The mechanistic studies indicate that in-situ-formed aldehydes react with a base through a Cannizzaro-type pathway, resulting in potassium hemiacetolate, which further underwent catalytic dehydrogenation to provide the carboxylate salts and H2. The experimental part of the paper was very detailed, including the reaction process of 2,6-Pyridinedimethanol(cas: 1195-59-1Recommanded Product: 2,6-Pyridinedimethanol)
2,6-Pyridinedimethanol(cas: 1195-59-1) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.Recommanded Product: 2,6-Pyridinedimethanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts