Category: alcohols-buliding-blocksIn 2022 ,《δ-C-H Halogenation Reactions Enabled by a Nitrogen-Centered Radical Precursor》 was published in Organic Letters. The article was written by Herron, Alastair N.; Hsu, Ching-Pei; Yu, Jin-Quan. The article contains the following contents:
Herein, new hydrazonyl carboxylic acids RN(S(O)2R1)N=C(Me)C(O)OH (R = octyl, 2-(adamantan-1-yl)ethyl, 4-methylpentyl, etc.; R1 = 4-methylphenyl, 4-methoxyphenyl, 4-bromophenyl, 4-(trifluoromethyl)phenyl) precursor to nitrogen-centered radicals and its application toward remote C-H fluorination and chlorination reactions of sulfonyl-protected alkyl amines R1S(O)2NHR2 (R2 = 4-fluorooctyl, 2-(2-fluorocyclobutyl)ethyl, 4-fluoro-4-methylpentyl, etc.) via 1,5-HAT were disclosed.6-Aminohexan-1-ol(cas: 4048-33-3Category: alcohols-buliding-blocks) was used in this study.
6-Aminohexan-1-ol(cas: 4048-33-3) can undergo cyclization over copper supported on γ-alumina and magnesia to form hexahydro-1H-azepine. It may be used along with glutaric acid to generate poly(ester amide)s with excellent film- and fiber forming properties.Category: alcohols-buliding-blocks
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts