Casnati, Alessandra; Lichosyt, Dawid; Lainer, Bruno; Veth, Lukas; Dydio, Pawel published their research in Organic Letters in 2021. The article was titled 《Multicatalytic Approach to One-Pot Stereoselective Synthesis of Secondary Benzylic Alcohols》.Reference of 5-Hexen-1-ol The article contains the following contents:
Here, one-pot, multicatalytic protocols that convert alkenes, unsaturated aliphatic alcs., and aryl boronic acids into secondary benzylic alcs. with high stereoselectivities (typically >95:5 er) under sequential catalysis that integrates alkene cross-metathesis, isomerization, and nucleophilic addn was reported. Prochiral allylic alcs. was converted to any stereoisomer of the product with high stereoselectivity (>98:2 er, >20:1 dr). The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Reference of 5-Hexen-1-ol)
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Reference of 5-Hexen-1-ol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts