In 2022,Balakrishnan, Venkadesh; Ganguly, Anirban; Rasappan, Ramesh published an article in Organic Letters. The title of the article was 《Interception of Nickel Hydride Species and Its Application in Multicomponent Reactions》.Recommanded Product: 100-55-0 The author mentioned the following in the article:
The hydrogen borrowing strategy is an economical method for the α-functionalization of ketones. While this strategy is extremely advantageous, it does not lend itself to the synthesis of β,β-disubstituted ketones. This can be achieved, if the in situ generated metal hydride can be intercepted with a nucleophilic coupling partner. Authors present a multicomponent strategy for the coupling of alcs., ketones, and boronic acids using only 1 mol % nickel catalyst and without the need for added ligands. In the experimental materials used by the author, we found 3-Pyridinemethanol(cas: 100-55-0Recommanded Product: 100-55-0)
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is a relatively complex molecule and exhibits a number of different bands in IR spectra. Among others, the bands characterizing the ν8a and ν19b modes have been found to be sensitive to the coordination or protonation of the molecule. Note that the band that is diagnostic for the PyH+ ion at about 1545 cm− 1 (ν19b mode) does not overlap with any of the other bands.Recommanded Product: 100-55-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts