On July 25, 1990, Gelling, Onko Jan; Meetsma, Auke; Feringa, Ben L. published an article.Related Products of 109486-06-8 The title of the article was Bimetallic oxidation catalysts. Synthesis, x-ray analysis, and reactivity of a binuclear p-hydroquinone-containing copper(II) complex. And the article contained the following:
A new pentadentate ligand I (H2L, R = 2-pyridyl) was prepared in steps from 2,6-dimethylphenol in 21% overall yield. Reaction of I with CuII(ClO4)2·6H2O gave the unexpectedly stable hydroquinone-containing [Cu2L(OH)](ClO4)2 (II). II crystallizes as triclinic, space group P1̅, a 9.399(2), b 10.469(1), c 14.612(4) Å, α 102.72(2), β 100.71(2), γ 104.60(2)°, Z = 2, R = 0.050, and Rw = 0.050. High reactivity of II was observed in catalytic oxidations of hydroquinones and α-hydroxy ketones using O2 as the oxidant. A mechanistic discussion is provided. The experimental process involved the reaction of 2,5-Dihydroxyisophthalaldehyde(cas: 109486-06-8).Related Products of 109486-06-8
The Article related to crystal structure copper dinuclear pyridylethyliminomethylhydroquinone, oxidation catalyst copper dinuclear pyridylethyliminomethylhydroquinone, copper dinuclear pyridylethyliminomethylhydroquinone complex, hydroquinone pyridylethyliminomethyl copper complex and other aspects.Related Products of 109486-06-8
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