Yadav, Vinita; Balaraman, Ekambaram; Mhaske, Santosh B. published an article in 2021. The article was titled 《Phosphine-Free Manganese(II)-Catalyst Enables Acceptorless Dehydrogenative Coupling of Alcohols with Indoles》, and you may find the article in Advanced Synthesis & Catalysis.Related Products of 100-55-0 The information in the text is summarized as follows:
Herein, an air-stable, molecularly defined NNN-Mn(II) pincer complex catalyzed acceptorless dehydrogenative coupling of alcs. with indoles is reported [e.g., 4-isopropylbenzyl alc. + indole → I (96%)]. A wide variety of sym. and unsym. bis(indolyl)methane derivatives as well as some structurally important products such as vibrindole A, turbomycin B alkaloid, antileukemic, and anticancer agents were synthesized. Mechanistic studies illustrate the importance of the NH moiety in the complex and the crucial role of metal-ligand cooperation during catalysis.3-Pyridinemethanol(cas: 100-55-0Related Products of 100-55-0) was used in this study.
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is a relatively complex molecule and exhibits a number of different bands in IR spectra. Among others, the bands characterizing the ν8a and ν19b modes have been found to be sensitive to the coordination or protonation of the molecule. Note that the band that is diagnostic for the PyH+ ion at about 1545 cm− 1 (ν19b mode) does not overlap with any of the other bands.Related Products of 100-55-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts