《Iron-Catalyzed Direct Julia-Type Olefination of Alcohols》 was written by Landge, Vinod G.; Babu, Reshma; Yadav, Vinita; Subaramanian, Murugan; Gupta, Virendrakumar; Balaraman, Ekambaram. Synthetic Route of C6H7NO And the article was included in Journal of Organic Chemistry in 2020. The article conveys some information:
Herein, we report an iron-catalyzed, convenient, and expedient strategy for the synthesis of styrene and naphthalene derivatives with the liberation of dihydrogen. The use of a catalyst derived from an earth-abundant metal provides a sustainable strategy to olefins. This method exhibits wide substrate scope (primary and secondary alcs.) functional group tolerance (amino, nitro, halo, alkoxy, thiomethoxy, and S- and N-heterocyclic compounds) that can be scaled up. The unprecedented synthesis of 1-Me naphthalenes proceeds via tandem methenylation/double dehydrogenation. Mechanistic study shows that the cleavage of the C-H bond of alc. is the rate-determining step. The experimental part of the paper was very detailed, including the reaction process of 3-Pyridinemethanol(cas: 100-55-0Synthetic Route of C6H7NO)
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is a relatively complex molecule and exhibits a number of different bands in IR spectra. Among others, the bands characterizing the ν8a and ν19b modes have been found to be sensitive to the coordination or protonation of the molecule. Note that the band that is diagnostic for the PyH+ ion at about 1545 cm− 1 (ν19b mode) does not overlap with any of the other bands.Synthetic Route of C6H7NO
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts