Koley, Debasis; De, Sriman; Sivendran, Nardana; Goossen, Lukas J. published an article in 2021. The article was titled 《Isomerization of Functionalized Olefins by Using the Dinuclear Catalyst [PdI(μ-Br)(PtBu3)]2: A Mechanistic Study》, and you may find the article in Chemistry – A European Journal.Recommanded Product: 5-Hexen-1-ol The information in the text is summarized as follows:
In a combined exptl. and computational study, the isomerization activity of the dinuclear palladium(I) complex [PdI(μ-Br)(PtBu3)]2 towards allyl arenes, esters, amides, ethers, and alcs. has been investigated. The calculated energy profiles for catalyst activation for two alternative dinuclear and mononuclear catalytic cycles, and for catalyst deactivation are in good agreement with the exptl. results. Comparison of exptl. observed E/Z ratios at incomplete conversion with calculated kinetic selectivities revealed that a substantial amount of product must form via the dinuclear pathway, in which the isomerization is promoted cooperatively by two palladium centers. The dissociation barrier towards mononuclear Pd species is relatively high, and once the catalyst enters the energetically more favorable mononuclear pathway, only a low barrier has to be overcome towards irreversible deactivation. After reading the article, we found that the author used 5-Hexen-1-ol(cas: 821-41-0Recommanded Product: 5-Hexen-1-ol)
5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Recommanded Product: 5-Hexen-1-ol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts