The author of 《Mediator and Additive Free Trifluoromethyl-Fluorination of Terminal Alkenes by Persistent Perfluoroalkyl Radical》 were Sato, Azusa; Ponomarenko, Maksym V.; Ono, Taizo; Roeschenthaler, Gerd-Volker; Soloshonok, Vadim A.. And the article was published in European Journal of Organic Chemistry in 2019. Related Products of 821-41-0 The author mentioned the following in the article:
It was found that the persistent perfluoro-3-ethyl-2,4-dimethyl-3-pentyl radical (PPFR) could serve as a source of both trifluoromethyl-radical and fluorine atom in the reactions with terminal olefins. The dual reactivity of the persistent PPFR allowed for both trifluoromethylation and fluorination of terminal olefins. This new approach towards di-functionalized 1-CF3-2-F-alkanes RCHFCH2CF3 [R = CH2HC(CO2Et)2, Bn, 3-ClC6H4CH2, etc.] demonstrated the widespread synthetic potential. Preliminary data strongly suggested potentially high synthetic value of this methodol. new transformation. The results came from multiple reactions, including the reaction of 5-Hexen-1-ol(cas: 821-41-0Related Products of 821-41-0)
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Related Products of 821-41-0
Referemce:
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Alcohols – Chemistry LibreTexts