The author of 《Matrix matters: Hyperbranched flame retardants in aliphatic and aromatic epoxy resins》 were Battig, Alexander; Markwart, Jens C.; Wurm, Frederik R.; Schartel, Bernhard. And the article was published in Polymer Degradation and Stability in 2019. Name: 5-Hexen-1-ol The author mentioned the following in the article:
Library of phosphorus-based flame retardants: phosphates and phosphoramides of low and high molar mass synthesis and their behavior investigation in two epoxy resins: one aliphatic and one aromatic The pyrolytic and burning behavior of the two resins (via TGA, TG-FTIR, Hot stage FTIR, Py-GC/MS, PCFC, DSC, LOI, UL-94, Cone calorimeter) are analyzed and compared to the results of flame retardant (FR)-containing composites. A decomposition pathway incorporating the identified modes of action and known chem. mechanisms is proposed. The overlap of decomposition temperature (Tdec) ranges of matrix and FR determines the efficacy of the system. Low molar mass FRs strongly impact material properties like Tg but are very reactive, and high molar mass variants are more thermally stable. Varying P-O and P-N content of the FR affects decomposition, but the chem. structure of the matrix also guides FR behavior. Thus, phosphates afford lower fire load and heat release in aliphatic epoxy resins, and phosphoramides can act as additives in an aromatic matrix or a reactive FRs in aliphatic ones. The chem. structure and the structure-property relationship of both FR and matrix are central to FR performance and must be viewed not as two sep. but as one codependent system. In the part of experimental materials, we found many familiar compounds, such as 5-Hexen-1-ol(cas: 821-41-0Name: 5-Hexen-1-ol)
5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Name: 5-Hexen-1-ol
Referemce:
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