《Elucidating the promotional effect of a covalent triazine framework in aerobic oxidation》 was published in Applied Catalysis, B: Environmental in 2020. These research results belong to Abednatanzi, Sara; Gohari Derakhshandeh, Parviz; Tack, Pieter; Muniz-Miranda, Francesco; Liu, Ying-Ya; Everaert, Jonas; Meledina, Maria; Vanden Bussche, Flore; Vincze, Laszlo; Stevens, Christian V.; Van Speybroeck, Veronique; Vrielinck, Henk; Callens, Freddy; Leus, Karen; Van Der Voort, Pascal. Application In Synthesis of 3-Pyridinemethanol The article mentions the following:
Synergistic catalysis holds great promise to enhance the catalytic performance of heterogeneous catalysts suffering from sluggish reaction kinetics. Much effort has been dedicated to the development of bimetallic systems in which the two promoter elements display synergistic benefits compared to monometallic counterparts. However, the use of bimetallic catalysts inescapably raises the cost of preparation and environmental issues. This study discovers a synergistic effect when using a bipyridine covalent triazine framework (bipy-CTF) as support for an IrIII complex in the aerobic oxidation reaction. The detailed mechanistic study provides insights into the function of the bipy-CTF in this synergistic catalysis. The EPR and in-situ XANES analyses confirm the applicability of bipy-CTF to activate oxygen and alc., resulting in an enhancement of the performance of the IrIII complex to exceed the activity of the homogeneous counterpart. This is an unprecedented report on promoting the activity of a heterogeneous catalyst through its solid support. The experimental part of the paper was very detailed, including the reaction process of 3-Pyridinemethanol(cas: 100-55-0Application In Synthesis of 3-Pyridinemethanol)
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is very deactivated towards electrophilic substitution with respect to benzene. For this reason classical formylation, using methods such as the Gattermann or Vilsmeier reactions, are not generally successful. Application In Synthesis of 3-Pyridinemethanol
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