Firsin, I. D.; Chuchelkin, I. V.; Gavrilov, V. K.; Trunina, V. M.; Zimarev, V. S.; Zheglov, S. V.; Gavrilov, K. N.; Goulioukina, N. S. published the artcile< Chiral P*,S-bidentate diamidophosphites with 1,2-thioether alcohol-based exocyclic substituents in asymmetric Pd-catalyzed reactions>, COA of Formula: C8H10OS, the main research area is chiral bidentate diamidophosphite thioether alc exocyclic palladium catalyst.
Chiral P*,S-diamidophosphites with a 1,3,2-diazaphospholidine core and exocyclic 1,2-hydroxyl-thioether fragments were prepared These asym. inducers provided up to 86% ee in the Pd-catalyzed allylic substitution of (E)-1,3-diphenylallyl acetate with di-Me malonate and pyrrolidine, and up to 76% in the Pd-mediated allylic alkylation of cinnamyl acetate with Et 2-oxocyclohexane-1-carboxylate.
Phosphorus, Sulfur and Silicon and the Related Elements published new progress about Allylic alkylation catalysts, stereoselective. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, COA of Formula: C8H10OS.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts