The author of 《Palladium oxide nanoparticles intercalated mesoporous silica for solvent free acceptorless dehydrogenation reactions of alcohols》 were Samanta, Partha Kumar; Ray, Shounak; Das, Trisha; Gage, Samuel H.; Nandi, Mahasweta; Richards, Ryan M.; Biswas, Papu. And the article was published in Microporous and Mesoporous Materials in 2019. Product Details of 100-55-0 The author mentioned the following in the article:
Aggregation-free well-dispersed palladium oxide nanoparticles intercalated into the walls of mesoporous silica (PdOMS) were prepared by using thioether groups during the sol-gel preparation of mesoporous silica. The PdOMS material was characterized by N2 adsorption-desorption, X-ray diffraction, SEM, transmission electron microscopy and UV-Vis spectroscopy. The material retains mesoporous structure with narrow pore size distribution with an average pore diameter of 6.8 nm and possesses high surface area of 683 m2g-1. The PdOMS catalyst was employed as an efficient heterogeneous catalyst in the acceptor- and oxidant-free dehydrogenation of neat alcs. to corresponding carbonyl compounds in very good to excellent yields (72-95%) at 80° under inert atm. The catalytic efficacy of PdOMS was evaluated for the acceptorless dehydrogenative coupling reactions of alcs. with o-diamino benzene and o-amino phenol to yield azole-based heterocycles. The stability of PdOMS was assessed by investigating its recyclability and reusability in the dehydrogenation of neat alc. for up to five cycles. After reading the article, we found that the author used 3-Pyridinemethanol(cas: 100-55-0Product Details of 100-55-0)
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine derivatives lend themselves to many roles in the spirited field of supramolecular chemistry – whether as the ligand backbone of metal-organic polymers or presiding over the key electronic stations of nanodevices. In biochemistry, pyridine-containing cofactors are necessary nutrients on which our lives depend. Product Details of 100-55-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts