In 2022,Mittal, Rupali; Awasthi, Satish Kumar published an article in ACS Sustainable Chemistry & Engineering. The title of the article was 《Bimetallic Oxide Catalyst for the Dehydrogenative Oxidation Reaction of Alcohols: Practical Application in the Synthesis of Value-Added Chemicals》.Synthetic Route of C6H7NO The author mentioned the following in the article:
This work demonstrates the preparation of zinc cobalt oxide materials (ZCO-1, ZCO-2, and ZCO-3) via thermal annealing of novel zinc cobalt acetate hydroxide precursors prepared in three different Co/Zn molar ratios (2:1, 1:1, and 1:2). Among these, the ZCO-1 sample displayed superior catalytic activity for the dehydrogenative oxidation of alcs. to carboxylic acids, exhibiting wide substrate applicability and high yield output with concomitant evolution of hydrogen gas (latent fuel) under oxidant-free conditions. The high catalytic activity of ZCO-1 can be accredited to synergistic effects arising from a balanced molar ratio of Co/Zn (2:1), which led to the formation of pure spinel-structured zinc cobalt oxide and a sufficiently high surface area capable of furnishing copious active sites, resulting in faster reaction kinetics and higher productivity. Moreover, the practical utility of the current protocol was displayed via ZCO-1-catalyzed gram-scale synthesis of value-added chems. like nicotinic acid, terephthalic acid, and succinic acid. In the part of experimental materials, we found many familiar compounds, such as 3-Pyridinemethanol(cas: 100-55-0Synthetic Route of C6H7NO)
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine’s structure is isoelectronic with that of benzene, but its properties are quite different. Pyridine is completely miscible with water, whereas benzene is only slightly soluble. Like all hydrocarbons, benzene is neutral (in the acid–base sense), but because of its nitrogen atom, pyridine is a weak base.Synthetic Route of C6H7NO
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts