Liu, YY; Xiong, J; Wei, L; Wan, JP in [Liu, Yunyun; Xiong, Jin; Wei, Li; Wan, Jie-Ping] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China published Switchable Synthesis of alpha,alpha-Dihalomethyl and alpha,alpha,alpha-Trihalomethyl Ketones by Metal-Free Decomposition of Enaminone C=C Double Bond in 2020, Cited 77. Application In Synthesis of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.
The novel free radical-based cleavage of the enaminone C=C double bond is realized by using N-halosuccinimides (NXS) in the presence of benzoyl peroxide (BPO) with mild heating, enabling the tunable synthesis of alpha,alpha-dihalomethyl ketones and alpha,alpha,alpha-trihalomethyl ketones under different reaction conditions. The formation of these divergent products involving featured C=C double bond cleavage requires no any metal reagent, and represents one more practical example on the synthesis of poly halogenated methyl ketones via the functionalization of carbon-carbon bond.
Application In Synthesis of (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Liu, YY; Xiong, J; Wei, L; Wan, JP or send Email.
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