I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article Tungsten-Catalyzed Direct N-Alkylation of Anilines with Alcohols published in 2021. COA of Formula: C8H10O2, Reprint Addresses Ke, ZF (corresponding author), Sun Yat Sen Univ, Sch Mat Sci & Engn, PCFM Lab, Guangzhou 510275, Peoples R China.; Liu, Y (corresponding author), Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol
The implementation of non-noble metals mediated chemistry is a major goal in homogeneous catalysis. Borrowing hydrogen/hydrogen autotransfer (BH/HA) reaction, as a straightforward and sustainable synthetic method, has attracted considerable attention in the development of non-noble metal catalysts. Herein, we report a tungsten-catalyzed N-alkylation reaction of anilines with primary alcohols via BH/HA. This phosphine-free W(phen)(CO)(4) (phen=1,10-phenthroline) system was demonstrated as a practical and easily accessible in-situ catalysis for a broad range of amines and alcohols (up to 49 examples, including 16 previously undisclosed products). Notably, this tungsten system can tolerate numerous functional groups, especially the challenging substrates with sterically hindered substituents, or heteroatoms. Mechanistic insights based on experimental and computational studies are also provided.
Welcome to talk about 105-13-5, If you have any questions, you can contact Lan, XB; Ye, ZR; Yang, CH; Li, WK; Liu, JH; Huang, M; Liu, Y; Ke, ZF or send Email.. COA of Formula: C8H10O2
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts