An article Enantioselective Protonation of Cyclic Carbonyl Ylides by Chiral Lewis Acid Assisted Alcohols WOS:000658032300001 published article about 1,3-DIPOLAR CYCLOADDITION REACTIONS; ASYMMETRIC CYCLOADDITIONS; RHODIUM; CARBENOIDS; DIAZOESTERS; COMPLEXES; CATALYSTS in [Toda, Yasunori; Yoshida, Takayuki; Arisue, Kaoru; Kikuchi, Ayaka; Suga, Hiroyuki] Shinshu Univ, Fac Engn, Dept Mat Chem, 4-17-1 Wakasato, Nagano 3808553, Japan; [Fukushima, Kazuaki; Esaki, Hiroyoshi] Hyogo Coll Med, Dept Chem, 1-1 Mukogawa Cho, Nishinomiya, Hyogo 6638501, Japan in 2021, Cited 60. Safety of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5
Chiral Lewis acid-catalyzed asymmetric alcohol addition reactions to cyclic carbonyl ylides generated from N-(alpha-diazocarbonyl)-2-oxazolidinones featuring a dual catalytic system are reported. Construction of a chiral quaternary heteroatom-substituted carbon center was accomplished in which the unique heterobicycles were obtained in good yields with high stereoselection. The alcohol adducts were successfully converted to optically active oxazolidine-2,4-diones by hydrolysis. Mechanistic studies by DFT calculations revealed that alcohols could be activated by Lewis acids, enabling enantioselective protonation of the carbonyl ylides.
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Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts