Safety of (4-Methoxyphenyl)methanol. In 2021 APPL ORGANOMET CHEM published article about C-H BONDS; CATALYZED ESTERIFICATION; COUPLING REACTIONS; CARBONYLATION; ALDEHYDES; CLEAVAGE; ESTERS; AMINATION; FUNCTIONALIZATION; ACTIVATION in [Dong, Jianyu; Mo, Min; Tang, Jian-Sheng] Hunan First Normal Univ, Dept Educ Sci, Changsha 410205, Peoples R China; [Dong, Jianyu; Chen, Xiuling; Ji, Fangyan; Liu, Lixin; Su, Lebin; Zhou, Yongbo] Hunan Univ, Coll Chem & Chem Engn, Changsha, Peoples R China; [Chen, Xiuling] Hubei Univ Sci & Technol, Nonpower Nucl Technol Collaborat Innovat Ctr, Sch Nucl Technol & Chem & Biol, Xianning, Peoples R China in 2021, Cited 79. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.
A simple and direct aerobic oxidative esterification reaction of arylacetonitriles with alcohols/phenols is achieved in the presence of a copper salt and molecular oxygen, which produces a broad range of aryl carboxylic acid esters in good to high yields. Copper salt plays multiple roles in the transformation, which allows the oxygenation of C-H bond, cleavage of inert C-C bond, and formation of C-O bond in one pot without the assistance of any of the acids, bases, ligands, and so on. The reaction provides a simple, direct, and efficient protocol towards functionalized esters, especially aryl benzoates, from readily available starting materials.
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Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts