HPLC of Formula: C8H10O2. Recently I am researching about CATALYZED N-ALKYLATION; C-C; AMINES; PHENALENYL; SPIN; EFFICIENT; AMIDES; HYDROAMINATION; ARYLAMINES; CHEMISTRY, Saw an article supported by the SERB (DST), India [EMR/2017/000772]; CSIR IndiaCouncil of Scientific & Industrial Research (CSIR) – India; IISER Kolkata. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Banik, A; Ahmed, J; Sil, S; Mandal, SK. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol
Borrowing hydrogen from alcohols, storing it on a catalyst and subsequent transfer of the hydrogen from the catalyst to an in situ generated imine is the hallmark of a transition metal mediated catalytic N-alkylation of amines. However, such a borrowing hydrogen mechanism with a transition metal free catalytic system which stores hydrogen molecules in the catalyst backbone is yet to be established. Herein, we demonstrate that a phenalenyl ligand can imitate the role of transition metals in storing and transferring hydrogen molecules leading to borrowing hydrogen mediated alkylation of anilines by alcohols including a wide range of substrate scope. A close inspection of the mechanistic pathway by characterizing several intermediates through various spectroscopic techniques, deuterium labelling experiments, and DFT study concluded that the phenalenyl radical based backbone sequentially adds H+, H and an electron through a dearomatization process which are subsequently used as reducing equivalents to the C-N double bond in a catalytic fashion.
HPLC of Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts