Recently I am researching about AEROBIC OXIDATIVE SYNTHESIS; CASCADE SYNTHESIS; QUINAZOLINONES; LIGANDS; FUNCTIONALIZATION; AMINOBENZAMIDES; BENZIMIDAZOLES; HYDROPEROXIDE; HETEROCYCLES; CHEMISTRY, Saw an article supported by the Indo-French Centre for the Promotion of Advanced Research (IFCPAR/CEFIPRA)Indo-French Centre for the Promotion of Advanced Research (IFCPAR/CEFIPRA) [5005-1]. Formula: C8H10O2. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Balaji, S; Balamurugan, G; Ramesh, R; Semeril, D. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol
A convenient protocol for the one-pot synthesis of quinazolin-4(3H)-ones using palladium(II) complexes via dehydrogenative coupling of readily available benzyl alcohols and 2-aminobenzamide has been described. New structurally related Pd(II) N boolean AND O chelating complexes of general configuration [Pd(L)Cl(PPh3)] (where L = dimethylamino benzoylhydrazone ligands) have been designed and synthesized. The formation of the complexes has been recognized by analytical and spectral methods (FT-IR, NMR, HR-MS). The presence of a square-planar geometry around the palladium(II) ion was confirmed by single crystal X-ray diffraction study. A wide range of substituted quinazolinones have been successfully achieved from a diverse range of benzyl alcohols in good to excellent yields using 1.0 mol % of catalyst loading under aerobic conditions. Furthermore, control experiments reveal that the dehydrogenative coupling reaction involves initially the formation of an aldehyde intermediate and subsequent formation of a cyclic aminal intermediate.
Formula: C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Balaji, S; Balamurugan, G; Ramesh, R; Semeril, D or send Email.
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts