An article Palladium-Catalyzed Oxidative Coupling of the Allenic C-H Bond with alpha-Diazo Esters: Synthesis of [3]Dendralenes WOS:000637001800043 published article about ALLYLIC ACETATES; MOLECULES in [Li, Shichao; Hou, Bo; Wang, Jianbo] Peking Univ, Coll Chem, Beijing Natl Lab Mol Sci BNLMS, Key Lab Bioorgan Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China in 2021, Cited 40. Recommanded Product: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5
A palladium-catalyzed highly regio- and stereoselective allenic C-H oxidative coupling with alpha-diazo esters is developed. The reaction pathway involves allylic palladium carbene as the key intermediate, which is followed by a carbene migratory insertion process. The reaction proceeds efficiently under mild conditions without external base, providing substituted [3]dendralenes bearing various functional groups.
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