Tag: M.W=100-200

Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 6920-22-5, Name is Hexane-1,2-diol, SMILES is CCCCC(O)CO, in an article , author is Tang, Xingfei, once mentioned of 6920-22-5, Product Details of 6920-22-5.

Improved hydrodeoxygenation of bio-oil model compounds with polymethylhydrosiloxane by Bronsted acidic zeolites

Bio-oil, one of significant renewable energy, was blocked from its direct application by thermodynamic instability due to the high oxygen content, so its deoxygenation needs urgent solution. Avoiding the disadvantages of the traditional catalytic method, such as harsh reaction conditions, potential explosion risk and environmental pollution, we utilize solid-acidic zeolites as low-load Pd-based catalyst supports instead of corrosive acid additives, with polymethylhydrosiloxane (PMHS) as the hydrogen-supplying agent, to achieve efficient hydro-deoxygenation of bio-oil models (carbonyl compounds) under mild conditions. The reaction conditions such as Si/Al ratio of HZSM-5 zeolite, temperature, solvent, and the type of Pd salts precursor are optimized. In particular, we have found that polar protic solvents improve catalytic efficiency by promoting proton transfer in the reaction. In an open-to-air, 97.9% ethylbenzene yield can be obtained for acetophenone conversion under mild conditions (0.5 wt% Pd/HZSM-5(18), 65 degrees C, 3 h, n-butanol as solvent), which is more efficient and environmental friendly than currently reports. Meanwhile, hydrogenation-dehydration mechanism was proposed, and the Brunsted acid in HZSM-5 promotes the dehydration of the alcohol (rate-limiting step) by efficiently accelerating the removal of hydroxyl groups and the proton transfer of the reaction. Furthermore, the catalytic scheme exhibits the excellent stability (reusable seven times) and versatility. The potential of a green catalytic technology using with PMHS opens attractive opportunities for bio-oil upgrading.

But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 6920-22-5, you can contact me at any time and look forward to more communication. Product Details of 6920-22-5.

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 6149-41-3, Name is Methyl 3-hydroxypropanoate, molecular formula is C4H8O3. In an article, author is Vakhrushev, Alexander Yu.,once mentioned of 6149-41-3, Product Details of 6149-41-3.

TiO2 and TiO2/Ag nanofibers: template synthesis, structure, and photocatalytic properties

A fairly simple method for the synthesis of TiO2 and TiO2/Ag fibers containing the anatase-rutile-silver heterojunction with a combination of features attractive for photocatalysis is presented.TiO2 and TiO2/Ag fibers were synthesized by impregnating a cellulose template with alcohol solutions of titanium(IV) tetrabutoxide and silver nitrate, followed by annealing at 500-950 degrees C. The microstructure of the fibers was analyzed by X-ray diffraction, scanning electronic microscopy, high-resolution transmission electronic microscopy and IR Fourier spectroscopy. The thermal decomposition of silver nitrate results in the formation of silver particles (19 +/- 3 nm), does not affect the crystallite size of anatase (19 +/- 3 nm) and rutile (23 +/- 3 nm), and promotes rutilization of TiO2. The photocatalytic activities of the obtained TiO2/Ag fibers were investigated by evaluating the phenol degradation under visible light irradiation. The highest catalytic activity was shown by mixed-phase samples consisting of 40% rutile and 60% anatase.

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Electric Literature of 115-70-8, Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. 115-70-8, Name is 2-Amino-2-ethylpropane-1,3-diol, SMILES is OCC(CC)(N)CO, belongs to alcohols-buliding-blocks compound. In a article, author is Ding, Yongjie, introduce new discover of the category.

Development of bio oil and bio asphalt by hydrothermal liquefaction using lignocellulose

Bio asphalt is an organic polymer derived from biomass resources, which has the potential to partially or completely replace petroleum asphalt. This study used lignocellulose to prepare bio oil by hydrothermal liquefaction method. A mixed solvent of ethanol and ethylene glycol was introduced to increase the oil yield and decrease the reaction temperature. The oil yield reached the highest when solvent mixing ratio of 1:1, liquid-solid ratio of 6:1, catalyst dosage of 3%, and reaction temperature of 250 degrees C respectively. The bio oil and 50# asphalt were mixed in proportion sheared for 30 min (1000 rpm) under the condition of 135 degrees C to produce bio asphalt. The chemical structures and rheological properties of bio oil and bio asphalt were investigated and compared with petroleum asphalt. Fourier transform infrared spectroscopy (FTIR) and Nuclear Magnetic Resonance analysis indicate that the bio oil expressed a lower H/C ratio, higher O content and more light components including liquid compounds comparing to the petroleum asphalt. The content of the polar group including O-H and C-O of bio oil was higher than that of petroleum asphalt. Gas Chromatography-Mass Spectrometry (GC-MS) was used to prove the presence of olefins and alcohols in bio oil. Thermogravimetric analysis showed that the bio oil expressed better thermal stability than that of petroleum asphalt, which expressed a potential of using as a pavement material. The dynamic shear rheometer (DSR) results showed that the complex shear modulus, G* decreased as the content of bio oil. The Glass transition temperature Tg indicated that the bio asphalt with 10% bio oil content showed similar performance with that of 70# asphalt. (C) 2020 Published by Elsevier Ltd.

Electric Literature of 115-70-8, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 115-70-8 is helpful to your research.

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One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, such as the rate of change in the concentration of reactants or products with time. 111-41-1, Name is N-(2-Hydroxyethyl)ethylenediamine, formurla is C4H12N2O. In a document, author is Li, Miao, introducing its new discovery. Formula: C4H12N2O.

Developing the QSPR model for predicting the storage lipid/water distribution coefficient of organic compounds

The distribution of organic compounds in stored lipids affects their migration, transformation, bioaccumulation, and toxicity in organisms. The storage lipid/water distribution coefficient (log K-lip/w) of organic chemicals, which quantitatively determines such distribution, has become a key parameter to assist their ecological security and health risk. Due to the impossibility to measure K-lip/w values for a huge amount of chemicals, it is necessary to develop predictive approaches. In this work, a quantitative structure-property relationship (QSPR) model for estimating log K-lip/w values of small organic compounds was constructed based on 305 experimental log K-lip/w values. Quantum chemical descriptors and n-octanol/water partitioning coefficient were employed to characterize the intermolecular interactions that dominate log K-lip/w values. The hydrophobic and electrostatic interactions and molecular size have been found to play important roles in governing the distribution of chemicals between lipids and aqueous phases. The regression (R-2 = 0.959) and validation (Q(2) = 0.960) results indicate good fitting performance and robustness of the developed model. A comparison with the predictive performance of other commercial software further proves the higher accuracy and stronger predictive ability of the developed K-lip/w predictive model. Thus, it can be used to predict the K-lip/w values of cycloalkanes, long-chain alkanes, halides (with fluorine, chlorine, and bromine as substituents), esters (without phosphate groups), alcohols (without methoxy groups), and aromatic compounds.

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Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 100-86-7, Name is 2-Methyl-1-phenyl-2-propanol, molecular formula is C10H14O. In an article, author is Abasalta, Mahdi,once mentioned of 100-86-7, SDS of cas: 100-86-7.

Fabrication of carboxymethyl chitosan/poly(epsilon-caprolactone)/doxorubicin/nickel ferrite core-shell fibers for controlled release of doxorubicin against breast cancer

The coaxial electrospinning for producing core-shell nanofibers due to control the release profile of drug by the shell layer has been developed. N-carboxymethyl chitosan (CMC)-polyvinyl alcohol (core)/poly(epsilon-caprolactone) (PCL) (shell) nanofibers were produced via coaxial electrospinning. Doxorubicin (DOX) and nickel ferrite nanoparticles were incorporated into the nanofibers for controlled release of DOX against MCF-7 breast cancer. The minimum CMC/PCL fiber diameter was found to be 300 nm by optimizing of three variables including voltage to distance ratio (1.5-2.5 kV/cm), CMC concentration (4-6 wt.%) and PCL concentration (8-12 wt.%). The synthesized core-shell fibers were characterized using FTIR, XRD, SEM, and TEM analysis. The extended release and controlled release of DOX from core-shell nanofibers were achieved under physiological pH without external magnetic field (EMF) and acidic pH with EMF during 25 and 7 days, respectively. The maximum cytotoxicity of MCF-7 breast cancer cells was about 83 % using CMC/PCL/nickel ferrite 10 % nanofibers and EMF.

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In an article, author is Akcan, Gizem, once mentioned the application of 112-27-6, Safety of 2,2′-(Ethane-1,2-diylbis(oxy))diethanol, Name is 2,2′-(Ethane-1,2-diylbis(oxy))diethanol, molecular formula is C6H14O4, molecular weight is 150.173, MDL number is MFCD00002880, category is alcohols-buliding-blocks. Now introduce a scientific discovery about this category.

The investigation of the mediating role of coping trategies on the relationship between childhood traumas, depression and alcohol use disorder in university students

The aim of this study is to investigate the mediating effect of coping strategies on the relationship among childhood traumas, depression, and alcohol use disorder in university students. The participants of this study consisted of 735 (209 males and 526 females) university students. Participants completed measures of depressive symptoms, childhood traumas, problematic alcohol consumption, and coping strategies as well as a socio-demographic information form. According to results, coping strategies fully mediated the relationship between childhood traumas and alcohol use disorder, and partially mediated the relationship between childhood traumas and depression.

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Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 623-50-7, Name is Ethyl 2-hydroxyacetate, molecular formula is C4H8O3, belongs to alcohols-buliding-blocks compound. In a document, author is Lin, Geng-Sheng, introduce the new discover, SDS of cas: 623-50-7.

A high ZIF-8 loading PVA mixed matrix membrane on alumina hollow fiber with enhanced ethanol dehydration

In this work, a zeolitic imidazolate framework-8 (ZIF-8)/polyvinyl alcohol (PVA) mixed matrix membrane (MMM) was coated onto a-aluminum oxide (alpha-Al2O3 ) hollow fibers for ethanol dehydration by utilizing the pervaporation technique. ZIF-8/PVA solution was prepared via a drying-free, water-based method to obtain a uniform distribution MMM. Before coating the MMM onto the hollow fiber, a pristine PVA solution was first dipcoated onto hollow fiber as a gutter layer to prevent phase separation. Different weight ratios of ZIF-8-loaded MMMs were prepared. The results showed that at high ZIF-8 loading (39 wt %), a high permeate flux (685 g/ m(2) h) and high separation factor (4821) can be observed. Furthermore, compared with free-standing ZIF-8/PVA MMMs, hollow fiber supported ZIF-8/PVA MMMs exhibit a thinner coating thickness but higher pervaporation separation index (approximately 1.5-2 times). The main contribution of this study is not only fabricated the high loading ZIF-8/PVA composite membrane with enhanced performance, but also coated onto the hollow fiber membrane which opens a gate for scale-up production.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 623-50-7. SDS of cas: 623-50-7.

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Synthetic Route of 770-71-8, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 770-71-8, Name is Adamantan-1-ylmethanol, SMILES is OCC12CC3CC(C2)CC(C3)C1, belongs to alcohols-buliding-blocks compound. In a article, author is Salih, Kifah S. M., introduce new discover of the category.

New tetradentate Schiff base Cu(II) complexes: synthesis, physicochemical, chromotropism, fluorescence, thermal, and selective catalytic oxidation

Three neutral Cu(II)/n(4)-NNNO Schiff base complexes (1-3) were prepared from the (E)-4-nitro-2-(((2-(piperazin-1-yl)ethyl)imino)methyl)phenol, tetradentate Schiff base (SB) ligand, and the corresponding copper(II) salts. The new SB and its complexes were fully characterized by CHN-EA, standard spectroscopic, thermal, and fluorescence analyses. The formation of the complexes was monitored by EDX, FT-IR, and UV-Vis. The chromotropism studies of the complexes reflected remarkable findings, in which bathochromic solvato- and thermochromism shifts were detected. The turn-off-on halochromism phenomena were observed in the acidic and basic medium. On the other hand, the fluorescence of the free SB ligand was turned off via complexation to the Cu(II) center. In the presence of H2O2 as green oxidant and under mild oxidation catalytic condition, the three complexes successfully catalyzed the formation benzaldehyde from benzyl alcohol.

Synthetic Route of 770-71-8, The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 770-71-8 is helpful to your research.

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Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. , SDS of cas: 3068-00-6, 3068-00-6, Name is 1,2,4-Butanetriol, molecular formula is C4H10O3, belongs to alcohols-buliding-blocks compound. In a document, author is Zhao, Guozhong, introduce the new discover.

Effect of Hericium erinaceus on bacterial diversity and volatile flavor changes of soy sauce

At present, the consumer demand for high-quality soy sauce is growing. Hericium erinaceus, an edible mushroom with many health benefits, was used for soy sauce fermentation. Firmicutes and Proteobacteria were identified as the main phyla, while, Bacillus and Stenotrophomonas as the predominant genera during soy sauce fermentation. H. erinaceus decreased the richness and diversity of bacteria during soy sauce fermentation due to its antimicrobial effect. Especially, Stenotrophomonas, a common opportunistic pathogen, was replaced by Bacillus during soy sauce fermentation by adding H. erinaceus. Moreover, H. erinaceus significantly promoted the esters and alcohols accumulation, and had positively influenced on a sensory constituent. However, pyrazines, ketones, and alkanes were rich in the control samples. Bacillus, Staphylococcus, and Psychrobacter showed a positive correlation to flavor formation with the addition of H. erinaceus. This study provided new insight into regulating the quality and microbial community of soy sauce by changing the raw material ingredients.

A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 3068-00-6. SDS of cas: 3068-00-6.

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Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, Category: alcohols-buliding-blocks4740-78-7, Name is 1,3-Dioxan-5-ol, SMILES is OC1COCOC1, belongs to alcohols-buliding-blocks compound. In a article, author is Raitasalo, Kirsimarja, introduce new discover of the category.

Smoke in the air – Associations between experimentation with cannabis and the use of tobacco and nicotine products among 15-16-year-old school students

Background: Cannabis is the most popular illicit drug among adolescents in developed countries, including Finland. The aim of this study was to estimate 1) how cannabis experimentation among Finnish adolescents changed between 2003 and 2019, and 2) whether the associations between cannabis experiments and factors related to it, especially the use of tobacco and nicotine products, changed during the same time period. Methods: The analyses are based on the European School Survey Project on Alcohol and Other Drugs data, collected from Finnish adolescents aged 15 to 16 in 2003, 2007, 2011, 2015, and 2019 (N = 20,630). Results: Experimentation with cannabis among Finnish adolescents has increased since the beginning of our follow-up. At the same time, alcohol use and smoking have decreased markedly, and attitudes toward cannabis use have become more relaxed. The association between smoking and cannabis experimentation has become weaker over time. However, the use of tobacco and nicotine products, especially polytobacco, is still a strong risk factor for experimentation with cannabis. The higher the number of tobacco or nicotine products used, the higher the probability for cannabis experimentation. Conclusions: Experimentation with cannabis has previously been concentrated predominantly on adolescents who smoke, but recently non-smokers are increasingly trying cannabis. It is possible that alternative ways of using cannabis may have increased its use. Despite the strict cannabis policy in Finland, its use has increased, which may be an indication that youth cultures and images of different substances play a significant role in adolescents experimenting with cannabis.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 4740-78-7. Category: alcohols-buliding-blocks.

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