Category: 770-71-8

Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 770-71-8, Name is Adamantan-1-ylmethanol, SMILES is OCC12CC3CC(C2)CC(C3)C1, in an article , author is Minhas, Meenu, once mentioned of 770-71-8, COA of Formula: C11H18O.

Multidimensional elements of impulsivity as shared and unique risk factors for food addiction and alcohol misuse

Food addiction (FA) and alcohol misuse tend to co-occur, which suggests shared factors in the etiology and persistence of these health behaviors. One shared factor that has been linked to both is impulsivity, a multidimensional construct reflecting multiple facets of self-regulatory capacity. However, co-occurrence also raises issues of possible confounding if both domains are not considered concurrently, and the intersection between FA, alcohol misuse, and impulsivity has not been well characterized empirically. Therefore, the current study examined the intersection of FA, alcohol consequences, and multiple indicators of impulsivity. Participants were emerging adults reporting regular heavy episodic drinking recruited from Hamilton, Ontario (N = 730; ages 19.5-23). Participants completed measures of FA, alcohol problems, impulsive personality traits (i.e., Barratt Impulsiveness Scales, UPPS-P Impulsive Behavior Scales), impulsive choice (i.e., delay discounting), impulsive action (i.e., Go/NoGo task). Findings revealed a significant association between FA and alcohol-related consequences and both shared similar associations with specific impulsive personality traits (Positive and Negative Urgency, Lack of Premeditation, Motor and Attentional Impulsivity). However, alcohol-related consequences were uniquely associated with other impulsive personality traits (Lack of Perseverance, Sensation Seeking, Non-planning impulsivity) and impulsive choice, and FA was uniquely associated with impulsive action. Beyond alcohol-related consequences, FA was associated with additional variance in measures of impulsive personality traits (Positive and Negative Urgency, Lack of Premeditation, Motor Impulsivity, and Attentional Impulsivity) and impulsive action, but not impulsive choice. Overall, the current study reveals several common self-regulatory processes associated with both adverse drinking consequences and FA, and that the risk of inadvertent confounding appears to be limited.

Interested yet? Read on for other articles about 770-71-8, you can contact me at any time and look forward to more communication. COA of Formula: C11H18O.

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Alcohol – Wikipedia,
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Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 770-71-8, Name is Adamantan-1-ylmethanol, molecular formula is C11H18O, belongs to alcohols-buliding-blocks compound, is a common compound. In a patnet, author is Wang, Jie, once mentioned the new application about 770-71-8, Product Details of 770-71-8.

Strong metal-support interaction induced O-2 activation over Au/MNb2O6 (M= Zn2+, Ni2+ and Co2+) for efficient photocatalytic benzyl alcohol oxidative esterification

A series of metal niobates (MNb2O6, M = Zn2+, Ni2+ and Co2+) were prepared from H-niobate precursor under hydrothermal conditions, in which amino groups of L-lysine play an important role. Au nanoparticles were then supported on these niobates by NaBH4 reduction method. More importantly, the strong interaction between Au nanoparticles and ZnNb2O6 generates negatively charged Au which can activate molecular oxygen to form the exclusive high-active peroxide (NbOOAu) species on Au/ZnNb2O6 surface under visible light irradiation, observed in situ by diffuse reflectance infrared Fourier transform spectra (DRIFTS). The optimal NbOOAu species produced on the surface of Au/ZnNb2O6 can remove the H atom of the methylene group (-CH2-) of benzyl alcohol, leading to high photocatalytic activity of Au/ZnNb2O6 compared with Au/NiNb2O6 and Au/CoNb2O6. This modulation of interaction of Au and niobates for the activation of molecular oxygen provides a new prospect for highly selective photocatalytic oxidation reactions.

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Reference of 770-71-8, In the chemical reaction process,reaction time,type of solvent,can easily affect the result of the reaction, thereby determining the yield and properties of the reaction product.An updated downstream synthesis route of 770-71-8 as follows.

Example 1 Synthesis of (chloromethyl) (1-adamantylmethyl) ether represented by a structural formula: A Kjeldahl flask having a volume of 50 ml equipped with a nozzle for introducing hydrogen chloride gas was charged with 1.66 g (10 mmol) of 1-adamantylmethanol, 0.60 g (20 mmol) of paraformaldehyde, 1.20 g (10 mmol) of magnesium sulfate and 30 ml of dried dichloromethane, and it was cooled to 0C on an ice bath and stirred. Hydrogen chloride gas generated by mixing 10 g of sodium chloride with 50 ml of conc. sulfuric acid was blown thereinto through the nozzle for one hour. After further stirring for 60 minutes, magnesium sulfate was filtered, and then the solution was analyzed by gas chromatography to confirm that 1-adamantylmethanol was completely converted and that the intended product was obtained at a selectivity of 94.5 %. Hydrogen chloride and dichloromethane were removed, and then refining was carried out by distillation to isolate 1.87 g (8.72 mmol, yield 87.2 %) of the intended product. The analytical results of the above compound are shown below. ¡¤Nuclear magnetic resonance spectrometry (NMR): CDCl31H-NMR (500 MHz): 1.53 (6H, f), 1.64 to 1.72 (6H, d), 1.97 (3H, e), 3.25 (2H, b), 5.50 (2H, a),13C-NMR (126 MHz): 28.18 (e), 37.11 (d or f), 39.45 (d or f), 33.49 (c), 81.34 (b), 84.25 (a) ¡¤Infrared spectrometry (IR): 2905 cm-1 (C-H; str.), 1157 cm-1 (C-O-C; str.), 650 cm-1 (C-Cl; str.) ¡¤ Boiling point (bp): 130 to 133C/0.7 kPa

These compound has a wide range of applications. It is believed that with the continuous development of the source of the synthetic route,770-71-8, its application will become more common.

Reference:
Patent; IDEMITSU KOSAN COMPANY LIMITED; EP1577285; (2005); A1;,
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Alcohols – Chemistry LibreTexts

Application of 770-71-8, With the rapid development and complex challenges of chemical substances, the synthesis of new drugs is usually one of the most effective ways to increase yield.770-71-8, name is Adamantan-1-ylmethanol, molecular formula is C11H18O, molecular weight is 166.26, as common compound, the synthetic route is as follows.

General procedure: To the solution of starting alcohol 2 (6 mmol) in dichloromethane(8 mL) was added Et3N (0.84 mL, 606 mg, 6 mmol) inatmosphere of Ar. The mixture was cooled to 0 to 5 C and theacryloyl chloride (0.49 mL, 543 mg, 6 mmol) in dichloromethane(2 mL) was added dropwise. The resulting mixture was stirred atthis temperature for 3 h and then at room temperature for 24 h.The reaction mixture was poured into water (15 mL) and extractedwith dichloromethane (4 20 mL). The combined organic layer waswashed with brine solution (3 20 mL) and was dried over anhydrousMg2SO4. The solvent was evaporated in vacuo; the residuewas purified by preparative column chromatography on silica gel.

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Reference:
Article; Averina, Elena B.; Vasilenko, Dmitry A.; Gracheva, Yulia A.; Grishin, Yuri K.; Radchenko, Eugene V.; Burmistrov, Vladimir V.; Butov, Gennady M.; Neganova, Margarita E.; Serkova, Tatyana P.; Redkozubova, Olga M.; Shevtsova, Elena F.; Milaeva, Elena R.; Kuznetsova, Tamara S.; Zefirov, Nikolay S.; Bioorganic and Medicinal Chemistry; vol. 24; 4; (2016); p. 712 – 720;,
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

770-71-8, With the rapid development and complex challenges of chemical substances, the synthesis of new drugs is usually one of the most effective ways to increase yield.770-71-8, name is Adamantan-1-ylmethanol, molecular formula is C11H18O, molecular weight is 166.26, as common compound, the synthetic route is as follows.

General procedure: To a solution of alcohol (1 mmol) in MeCN-H2O (9:1, 3 mL) were successively added TEMPO (7.8 mg,5 mol%), NH4OAc (0.308 g, 4 equiv), and PhI(OAc)2 (0.708g, 2.2 equiv). The suspension was stirred at roomtemperature (progress of the reaction was monitored byTLC) for the reaction time indicated in Table 2. The resultantclear two-phase reaction mixture was concentrated, dilutedwith H2O and Et2O, and the organic layer was dried (Na2SO4), filtered, and evaporated under reduced pressure.The residue was purified by flash column chromatography(PE-Et2O or PE-CH2Cl2) to give 2.

Statistics shows that 770-71-8 is playing an increasingly important role. we look forward to future research findings about Adamantan-1-ylmethanol.

Reference:
Article; Vatele, Jean-Michel; Synlett; vol. 25; 9; (2014); p. 1275 – 1278;,
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Adding a certain compound to certain chemical reactions, such as: 770-71-8, Adamantan-1-ylmethanol, can increase the reaction rate and produce products with better performance than those obtained under traditional synthetic methods. Here is a downstream synthesis route of the compound, 770-71-8, blongs to alcohols-buliding-blocks compound. 770-71-8

Example 57A 1-(azidomethyl)tricyclo[3.3.1.13,7]decane 1-Adamantanemethanol (500 mg) was dissolved in dichloromethane (15 mL). The solution was chilled in an ice bath and triethylamine (0.587 mL) was added, followed by methanesulfonyl chloride (0.258 mL). The reaction mixture was stirred for 4 hours at 0 C., then transferred to a separatory funnel and rinsed with 1N aqueous HCl (15 mL), saturated aqueous NaHCO3 (15 mL) and brine (15 mL). The organic extracts were dried (Na2SO4), filtered, and concentrated. A portion of the resulting crude mesylate (293 mg) and sodium azide (390 mg) were combined in N,N-dimethylformamide (1.2 mL) and the reaction mixture was heated to 120 C. overnight, then cooled to room temperature and partitioned between ethyl acetate (3*15 mL) and water (20 mL). The organic extracts were dried (Na2SO4), filtered, and concentrated to provide the title compound, which was used in the next step without further purification.

These compound has a wide range of applications. It is believed that with the continuous development of the source of the synthetic route,770-71-8, its application will become more common.

Reference:
Patent; AbbVie Inc.; WANG, LE; Doherty, George; Wang, Xilu; Tao, Zhi-Fu; Bruncko, Milan; Kunzer, Aaron R.; Wendt, Michael D.; Song, Xiaohong; Frey, Robin; Hansen, Todd M.; Sullivan, Gerard M.; Judd, Andrew; Souers, Andrew; US2013/96120; (2013); A1;,
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

770-71-8, Adding a certain compound to certain chemical reactions, such as: 770-71-8, Adamantan-1-ylmethanol, can increase the reaction rate and produce products with better performance than those obtained under traditional synthetic methods. Here is a downstream synthesis route of the compound, 770-71-8, blongs to alcohols-buliding-blocks compound.

Preparation 7.2 Adamant-1-ylmethyl methanesulfonate (III) A mixture of 3 g of adamantan-1-ylmethanol and 5 ml of triethylamine in 50 ml of DCM is cooled to 0 C., 2 ml of methanesulfonyl chloride are added dropwise, and the mixture is left to stir while allowing the temperature to return to AT. A mixture of water/ice is added to the reaction mixture, the mixture is extracted with DCM, the organic phase is dried over Na2SO4, and the solvent is evaporated off under vacuum. 2 g of the expected compound are obtained.

These compound has a wide range of applications. It is believed that with the continuous development of the source of the synthetic route,770-71-8, its application will become more common.

Reference:
Patent; SANOFI-AVENTIS; US2009/281107; (2009); A1;,
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

770-71-8, With the rapid development and complex challenges of chemical substances, the synthesis of new drugs is usually one of the most effective ways to increase yield.770-71-8, name is Adamantan-1-ylmethanol, molecular formula is C11H18O, molecular weight is 166.26, as common compound, the synthetic route is as follows.

Preparation of 1-Bromomethyladamantane, IV To 1-Hydroxymethyladamantane (366 gm.) and triphenylphosphine (598 gm.) in 1600 ml. dimethylformamide was added a solution of 366 gm. bromine in 800 ml. dimethylformamide over a 5 hour period. The mixture was left overnight at room temperature and then distilled (under aspirator) to remove solvent and product. The distillate was poured into 8 liters of water and filtered. The solid was dissolved in petroleum ether (30-60), washed with K2 CO3 solution, then with water, dried, and concentrated to dryness. The residue recrystallized from 2.5 liters methanol gave 426.6 gm., m.p. 43-4. (1st crop plus additional crops obtained on concentration of the mother liquors.)

Statistics shows that 770-71-8 is playing an increasingly important role. we look forward to future research findings about Adamantan-1-ylmethanol.

Reference:
Patent; Pennwalt Corporation; US4100170; (1978); A;,
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts