Month: October 2022

Application of 4048-33-3In 2022 ,《POSS-containing polynorbornene with pendant perylene diimide: from a unique supramolecular structure to tunable luminescence properties》 appeared in Journal of Materials Chemistry C: Materials for Optical and Electronic Devices. The author of the article were Liu, Jie; Gao, Si-Yu; Zhang, Xin-Yi; Feng, Yakai; Wu, Han-Chun; Chen, Zhijian; Bermeshev, Maxim V.; Ren, Xiang-Kui. The article conveys some information:

POSS-containing polynorbornene with pendant perylene diimide (PPDI-POSS) has been synthesized, with alkyl-containing polynorbornene (PPDI-C10C8) as the reference The supermol. structure and photoluminescence properties were elucidated using UV-Vis absorption spectra, and one- and two-dimensional X-ray diffraction. The exptl. results reveal that PPDI-C10C8 possesses a lamellar structure with close PDI stacking to meet the requirement for min. free energy. However, the introduction of POSS cages endows PPDI-POSS with a unique hexagonal columnar structure and enhanced photoluminescence properties due to the steric hindrance of POSS cages. These results may contribute to the understanding of the structure-property relationship of the optical polymers and provide some useful information for the design of polymer materials with a controllable supramol. structure and tunable luminescence properties. In the experimental materials used by the author, we found 6-Aminohexan-1-ol(cas: 4048-33-3Application of 4048-33-3)

6-Aminohexan-1-ol(cas: 4048-33-3) can undergo cyclization over copper supported on γ-alumina and magnesia to form hexahydro-1H-azepine. It may be used along with glutaric acid to generate poly(ester amide)s with excellent film- and fiber forming properties.Application of 4048-33-3

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《Salen-porphyrin-based conjugated microporous polymer supported Pd nanoparticles: highly efficient heterogeneous catalysts for aqueous C-C coupling reactions》 was published in Journal of Materials Chemistry A: Materials for Energy and Sustainability in 2019. These research results belong to Ju, Pengyao; Wu, Shujie; Su, Qing; Li, Xiaodong; Liu, Ziqian; Li, Guanghua; Wu, Qiaolin. Computed Properties of C12H14O3 The article mentions the following:

The salen-porphyrin based conjugated microporous polymer (SP-CMP) was first constructed by polycondensation reaction of a salen-dialdehyde derivative and pyrrole. Due to the outstanding chem. and thermal stability, abundant micropores with a reasonable pore size, and ordered salen-porphyrin arrays in the A4B4-type polymer framework, the functional CMP was further applied as a Pd nanoparticle support by the coordinate interactions between the polydentate chelating sites with Pd(OAc)2 and subsequent reduction with NaBH4. The as-synthesized composite material (Pd@SP-CMP) was fully characterized by powder X-ray diffraction (PXRD), thermogravimetric anal. (TGA), Fourier transform IR (FT-IR) spectroscopy, XPS, and solid-state 13C NMR (NMR). The porous property of Pd@SP-CMP was also characterized by N2 adsorption/desorption isotherms and the obtained material exhibited a Brunauer-Emmett-Teller (BET) surface area of 266 m2 g-1, together with a pore volume of 0.192 cm3 g-1. The microscopic morphol. of Pd@SP-CMP was further evaluated by SEM (SEM) and transmission electron microscopy (TEM). The Pd@SP-CMP material with highly dispersed Pd nanoparticles exhibited excellent catalytic activity towards Suzuki-Miyaura and Heck-Mizoroki coupling reactions in water or in the dioxane/water mixture In addition, Pd@SP-CMP also displayed outstanding stability and recyclability, and it can be reused without loss of activity in ten successive reactions. More importantly, the salen-porphyrin based CMPs could be the promising candidates for developing high-performance heterogeneous catalysts. In the experimental materials used by the author, we found 5-(tert-Butyl)-4-hydroxyisophthalaldehyde(cas: 153759-59-2Computed Properties of C12H14O3)

5-(tert-Butyl)-4-hydroxyisophthalaldehyde(cas: 153759-59-2) belongs to phenols.Computed Properties of C12H14O3Deprotonation of a phenol forms a corresponding negative phenolate ion or phenoxide ion, and the corresponding salts are called phenolates or phenoxides (aryloxides according to the IUPAC Gold Book).

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Alcohol – Wikipedia,
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《Tuning proton dissociation energy in proton carrier doped 2D covalent organic frameworks for anhydrous proton conduction at elevated temperature》 was written by Chen, Shuhui; Wu, Yue; Zhang, Ying; Zhang, Wenxiang; Fu, Yu; Huang, Wenbo; Yan, Tong; Ma, Heping. Category: alcohols-buliding-blocksThis research focused ontwo dimentional covalent organic framework proton conduction. The article conveys some information:

A theor. and exptl. study gives insights into the change of proton dissociation energy of anhydrous proton carriers (phosphoric acid and 1,2,4-triazole) doped in 2D covalent organic frameworks (COFs) with neutral, polar, Lewis base and pos. charged sites in their 1D channels. The dielec. properties of proton carrier incorporated COFs were investigated to determine the formation of nanoscale ionic phases in COFs′ channels. The proton carrier doped cationic COF exhibits a much higher dielec. constant in the frequency range of 103 Hz to 107 Hz than other doped COFs, which may arise from the formation of ethidium-biphosphate or ethidium-triazole ion-pairs in charged COF channels. The ion-pairs lined along cationic COFs′ channels produce an enhanced proton dissociation degree coupled with a high dielec. response, leading to a new proton conductivity record (2.77 x 10-2 S cm-1) set by the cationic COF among all reported porous materials under anhydrous conditions and elevated temperatures After reading the article, we found that the author used 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Category: alcohols-buliding-blocks)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives. Phloroglucinol derivatives are a major class of secondary metabolites. Phloroglucinol compounds can be classified into monomeric, dimeric, trimeric and higher phloroglucinols, and phlorotannins.Category: alcohols-buliding-blocks

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Alcohol – Wikipedia,
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In 2019,Research Journal of Pharmaceutical, Biological and Chemical Sciences included an article by Ivanchenko, Dmytro; Romanenko, Mykola; Goloborodko, Oleksandr; Kamyshnyi, Oleksandr; Polishchuk, Natalia. HPLC of Formula: 13325-10-5. The article was titled 《Synthesis and biological activity of 8-aminosubstituted 7-(2-hydroxy-3-methylphenoxypropyl-1)-3-methylxanthine》. The information in the text is summarized as follows:

The reaction of 8-bromo-3-methylxanthine with m-ethylphenoxymethyloxirane in propanol-1 medium in the presence of N,N-dimethylbenzylamine led to formation of 8-bromo-7-(2-hydroxy-3-methylphenoxypropyl-1)-3-methylxanthine which was then interacted with amines to afford 8-aminosubstituted 7-(2-hydroxy-3-m-ethylphenoxypropyl-1)-3-methylxanthines I [R1 = H, Me, Et; R2 = Me, n-Pr, cyclohexyl, etc.]. Structures of the synthesized compounds I were proved by 1H NMR-spectroscopy. The synthesized compounds I revealed moderate to weak antibacterial and antifungal activities in concentrations 50-200 mcg/mL. The experimental process involved the reaction of 4-Aminobutan-1-ol(cas: 13325-10-5HPLC of Formula: 13325-10-5)

4-Aminobutan-1-ol(cas: 13325-10-5) is used in the synthesis of NSAIDs with anti-inflammatory properties. Also used in the synthesis of polyamine transport ligands with specificity against human cancers allowing easy access to specific cancer cells.HPLC of Formula: 13325-10-5

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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Journal of Materials Chemistry A: Materials for Energy and Sustainability included an article by Liu, Chuanyao; Jiang, Yunzhe; Nalaparaju, Anjaiah; Jiang, Jianwen; Huang, Aisheng. Product Details of 34374-88-4. The article was titled 《Post-synthesis of a covalent organic framework nanofiltration membrane for highly efficient water treatment》. The information in the text is summarized as follows:

Nanofiltration (NF) membranes with ultrahigh water flux and high ion rejection are substantially beneficial for desalination and wastewater treatment. However, synthesis of NF membranes with high water permeance while maintaining high ion rejection remains a great challenge. Herein, we report a highly stable covalent organic framework (COF) IISERP-COOH-COF1 membrane with high ion rejection and relatively high water flux. Through post-modification, the pore aperture of the IISERP-COOH-COF1 membrane can be constricted, thus preventing ions from accessing the pores. Further, covalent post-functionalization is helpful to reduce non-selective transport through invisible intercrystalline defects, thus enhancing salt rejection. Demonstrated by both exptl. and simulation studies, the IISERP-COOH-COF1 membrane shows superior ion rejection (e.g., 96.3% for Na2SO4, 97.2% for MgSO4, 99.6% for FeCl3, 90.6% for MgCl2, and 82.9% for NaCl) based on size exclusion, with a water flux above 0.5 L m-2 h-1 bar-1. In addition to this study using 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde, there are many other studies that have used 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Product Details of 34374-88-4) was used in this study.

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives.Product Details of 34374-88-4For acyl phloroglucinols, it is considered the largest category of compounds among phloroglucinols of natural characteristics.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Journal of Materials Chemistry A: Materials for Energy and Sustainability included an article by Wang, Hongjian; Chen, Long; Yang, Hao; Wang, Meidi; Yang, Leixin; Du, Haiyan; Cao, Chenliang; Ren, Yanxiong; Wu, Yingzhen; Pan, Fusheng; Jiang, Zhongyi. Reference of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde. The article was titled 《Bronsted acid mediated covalent organic framework membranes for efficient molecular separation》. The information in the text is summarized as follows:

Covalent organic frameworks (COFs) hold great promise in mol. separation However, since the aperture size of most COFs is in the range of 0.8-4.9 nm, constructing COF membranes with a smaller aperture size is thus in urgent demand yet remains a grand challenge. In this study, a Bronsted acid mediated one-step self-assembly method for the fabrication of COF membranes is proposed by segregating the organic phase (containing Bronsted acids and aldehydes) from the aqueous phase (containing amines) with a polymeric support and implementing an interfacial polymerization reaction thereby. Bronsted acids, serving as a versatile mediator, can facilitate the amorphous-to-crystalline transformation, ensure the confined membrane growth at the interface and regulate the assembly behavior of COF subunits, and thus play a critical role in manipulating the microstructure evolution of COF-JLU2 membranes. More intriguingly, a correlation among membrane structures, separation performance and the partition coefficient (log P) of Bronsted acids was established. When log P lies in between 1.0 and 3.0, the COF membranes with continuous active layers, tunable thickness (50-400 nm) and small aperture size (0.49-0.51 nm) can be fabricated, achieving superior alc. dehydration performances to all the reported membrane counterparts. Our findings may stimulate further research on bottom-up construction of COF membranes and other kinds of organic framework membranes (XOF membranes). In the experiment, the researchers used many compounds, for example, 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Reference of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives.Reference of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehydePhloroglucinols are known for their broad-spectrum antiviral, antibacterial, antifungal, antihelminthic, and phytotoxic activities.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2022,Xia, LiangLiang; Tu, HongJun; Zeng, Wen; Yang, XiaoLing; Zhou, Ming; Li, Linkai; Guo, Xiao published an article in Journal of Materials Chemistry A: Materials for Energy and Sustainability. The title of the article was 《A room-temperature self-healing elastomer with ultra-high strength and toughness fabricated via optimized hierarchical hydrogen-bonding interactions》.Safety of 2,6-Pyridinedimethanol The author mentioned the following in the article:

The preparation of room-temperature self-healing polymeric materials with good healing efficiency and high mech. strength is challenging. Two processes are essential to realize the room-temperature self-healing of materials: (a) a non-crystallized structure and interpenetration and diffusion of polymer chains; (b) fast reorganization of the intermol. bonds at damaged sites. Using these strategies, a new polyurethane elastomer is prepared in this study via three-step polyadditions using polytetramethylene ether glycol, isophorone diisocyanate, 2,6-pyridinedimethanol, and 4,4′-methylene bis(2-chloroaniline). The prepared elastomer possesses excellent tensile strength (34.1 MPa), high toughness (127.3 MJ m-3), high fracture energy (119.1 kJ m-2), and good stretchability (2014%). Furthermore, it exhibits strain-induced strengthening behavior and its mech. performances are superior to those of previously reported room-temperature self-healing polymer materials. The polyurethane elastomer synthesized via optimized hierarchical H-bonding interactions ultimately exhibited a synchronous self-healing efficiency of more than 83% with tensile strength, elongation, and toughness at 25°C ± 2°C after self-healing for 48 h. This study offers beneficial insights into the preparation of room-temperature self-healing polymers with high mech. strength. In the experiment, the researchers used many compounds, for example, 2,6-Pyridinedimethanol(cas: 1195-59-1Safety of 2,6-Pyridinedimethanol)

2,6-Pyridinedimethanol(cas: 1195-59-1) belongs to pyridine. Pyridine is very deactivated towards electrophilic substitution with respect to benzene. For this reason classical formylation, using methods such as the Gattermann or Vilsmeier reactions, are not generally successful. Safety of 2,6-Pyridinedimethanol

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Alcohol – Wikipedia,
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Smolobochkin, Andrey V.; Yakhshilikova, Lola Zh.; Gazinov, Almir S.; Vagapova, Liliya I.; Burilov, Alexander R.; Pudovik, Michael A. published an article in Chemistry of Heterocyclic Compounds (New York, NY, United States). The title of the article was 《Synthesis of novel macrocyclic and heterocyclic taurine derivatives based on the reaction of sodium 2-[(4,4-diethoxybutyl)amino]ethanesulfonate with phenols》.Recommanded Product: 4,4-Diethoxybutan-1-amine The author mentioned the following in the article:

An approach to the synthesis of novel macrocyclic and heterocyclic taurine derivatives I and II (R = H, Me, OH) based on the reaction of sodium 2-[(4,4-diethoxybutyl)amino]ethanesulfonate with phenols 2-R-3-OHC6H3OH in the presence of trifluoroacetic acid has been developed. In addition to this study using 4,4-Diethoxybutan-1-amine, there are many other studies that have used 4,4-Diethoxybutan-1-amine(cas: 6346-09-4Recommanded Product: 4,4-Diethoxybutan-1-amine) was used in this study.

4,4-Diethoxybutan-1-amine(cas: 6346-09-4) belongs to anime. Large quantities of aliphatic amines are made synthetically. The most widely used industrial method is the reaction of alcohols with ammonia at a high temperature, catalyzed by metals or metal oxide catalysts (e.g., nickel or copper). Mixtures of primary, secondary, and tertiary amines are thereby produced.Recommanded Product: 4,4-Diethoxybutan-1-amine

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Alcohol – Wikipedia,
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《Iridium(III) complex-containing non-conjugated polymers for non-volatile memory induced by switchable through-space charge transfer》 was written by Yang, Baojie; Tao, Peng; Ma, Chenxi; Tang, Runze; Gong, Tao; Liu, Shujuan; Zhao, Qiang. Related Products of 627-18-9 And the article was included in Journal of Materials Chemistry C: Materials for Optical and Electronic Devices in 2020. The article conveys some information:

Organic memory devices have recently attracted considerable interest to combat the increasing demands of data storage. Herein, taking advantage of the electron-deficient nature of iridium(III) complexes and the flexible polymer skeleton of non-conjugated polymers, a series of novel non-conjugated iridium(III) complex-containing polymers P2-P5 with non-volatile memory properties, and the corresponding model polymer P1, were rationally designed and synthesized. The memory effect of P1 is a static random-access memory type, while that of the polymers containing iridium(III) complexes are flash types. The ON/OFF current ratio of the devices based on P3 is as high as 103 and the device has good stability. It exhibits a long retention time of 104 s and both ON and OFF states, which survive up to more than 105 read cycles. The introduction of an iridium(III) complex contributes to the charge-transfer states from carbazole moieties to the iridium(III) complex, which also improves the crystallinity of polymers and realizes elec. bistability. In the part of experimental materials, we found many familiar compounds, such as 3-Bromopropan-1-ol(cas: 627-18-9Related Products of 627-18-9)

3-Bromopropan-1-ol(cas: 627-18-9) is used in the synthesis of fluorescent halide-sensitive quinolinium dyes, chiral, quaternary prolines through cyclization of quaternary amino acids and molten salt-polymers. It is utilized for the study of micellar media and in microemulsions based on cationic or a nonionic surfactant by reacting with phenols.Related Products of 627-18-9

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Category: alcohols-buliding-blocksIn 2018 ,《Deciphering the potentiometric properties of (porphinato)zinc(II)-derived supramolecular polymers and related superstructures》 appeared in Journal of Materials Chemistry C: Materials for Optical and Electronic Devices. The author of the article were Liu, Chuan; Liu, Kaixuan; Klutke, Jared; Ashcraft, Adam; Steefel, Samantha; Olivier, Jean-Hubert. The article conveys some information:

Because modulating the structure-function relationships of π-conjugated superstructures opens fresh opportunities to tune the electronic structures of semiconducting materials, self-assembled architectures have emerged as pivotal candidates to engineer optoelectronic devices. While the photophys. and elec. properties of 1-dimensional supramol. polymers have been extensively explored, establishing their fundamental potentiometric properties using reliable electrochem. measurements has been less scrutinized and would benefit the engineering of semiconducting materials. In this regard, elucidating the energy level of valence and conduction bands that delineate the electronic structure of self-assemblies is critical to unveiling the parameters that regulate their structure-function properties. In the present contribution, design principles to engineer 2-dimensional nanosheets, nanowires, fibers and amorphous solids from (porphinato)zinc(II) (PZn) building blocks have been elucidated by modifying the structural properties of the side chains that flank PZn-based cores. As these self-assemblies feature identical redox-active building blocks but evidence different solid-state morphologies, the elucidation of their potentiometric properties reveals important structural parameters that regulate the potentials at which holes and electrons are injected into the valence and conduction bands of these hierarchical materials. While self-assembly conformations modestly impact valence band energies, superstructures built from H-type aggregates feature a conduction band energy stabilized by more than 350 meV with respect to those constructed from J-type aggregates. In the experiment, the researchers used many compounds, for example, 3,5-Dihydroxybenzaldehyde(cas: 26153-38-8Category: alcohols-buliding-blocks)

3,5-Dihydroxybenzaldehyde(cas: 26153-38-8) is a building block. It has been used in the synthesis of 2,4-dimethylbenzoylhydrazones with antileishmanial and antioxidant activities.Category: alcohols-buliding-blocks

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Alcohol – Wikipedia,
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