Category: 12080-32-9

Synthetic Route of C8H12Cl2Pt. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about C,C coordination mode in comparison with C,P coordination mode in six and seven pallada- and platinacycle complexes of phosphorous ylide; synthesis, X-ray and theoretical studies. Author is Sedghi, Asieh; Sabounchei, Seyyed Javad; Yousefi, Abed; Sayadi, Mohsen; Bayat, Mehdi; Gable, Robert W..

New sym. [p-CN-C6H4C(O)CH2PPh2(CH2)2PPh2CH2C(O)C6H4-p-CN]Br2(1) and unsym. [PPh2(CH2)2PPh2CH2C(O)C6H4-p-CN]Br (2) phosphonium salts were prepared by reacting Bis(diphenylphosphino)ethane (dppe) with p-CN-C6H4C(O)CH2Br in acetone, in 1:2 and 1:1 ratios, resp. Treatment of these salts with an appropriate alkali led to sym. p-CN-C6H4C(O)C(H)PPh2(CH2)2PPh2C(H)C(O)C6H4-p-CN (3) and unsym. PPh2(CH2)2PPh2C(H)C(O)C6H4-p-CN (4) ylides. The reaction of 3 and 4 with [MCl2(cod)] (M = Pd or Pt; cod = 1,5-cyclooctadiene) in 1:1 ratio, using dichloromethane as a solvent, led to mononuclear seven membered metallocyclic ring complexes [MCl2(p-CN-C6H4C(O)C(H)PPh2(CH2)2PPh2C(H)C(O)C6H4-p-CN)] (M = Pd (5) and Pt (6), having C,C coordination mode) and mononuclear six membered ring complexes [MCl2(PPh2(CH2)2PPh2C(H)C(O)C6H4-p-CN)] (M = Pd (7) and Pt (8), having P,C coordination mode), resp. Characterization of the resulting compounds were performed by elemental anal., IR, 1H,13C and 31P NMR spectroscopic methods. As well, the unequivocal structure of compound 5 (seven membered pallada-cycle complex) was characterized crystallog. In the sym. complexes, with seven membered metallocyclic rings, the title ylide is coordinated to the metal through two ylidic carbon atoms. Using theor. methods, D.-function theory (DFT) calculations at the BP86/def2-SVP level of theory, the structures of the unsym. six membered pallada- and platinacyclic complexes were compared with the structures of the sym. seven membered pallada- and platinacyclic complexes. The strength and nature of donor-acceptor bonds between the phosphorus ylide (Y ligand) and MCl2 fragments in the [YMCl2] M = Pd, Pt, Y = p-CN-C6H4C(O)C(H)PPh2(CH2)2PPh2C(H)C(O)C6H4-p-CN,PPh2(CH2)nPPh2C(H)C(O)C6H4-p-CN, n = 1-2, were carried out by Natural bond orbital anal. (NBO) and energy-decomposition anal. (EDA) as well as their natural orbitals for chem. valence (NOCV) variations.

From this literature《C,C coordination mode in comparison with C,P coordination mode in six and seven pallada- and platinacycle complexes of phosphorous ylide; synthesis, X-ray and theoretical studies》,we know some information about this compound(12080-32-9)Synthetic Route of C8H12Cl2Pt, but this is not all information, there are many literatures related to this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Related Products of 12080-32-9. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Photochemistry of 1,5-Cyclooctadiene Platinum Complexes for Photoassisted Chemical Vapor Deposition.

Quantum yields for disappearance of (COD)PtMe2 (1a) and (COD)PtMeCl (1b) were determined at 334 nm in C6D6 solvent. Chain reactions initiated by formation of a Me radical were proposed to be the cause of quantum yields higher than unity (Φ = 5.52 ± 0.40 for 1a) when the reaction mixtures included C4F9I. The chain reactions were suppressed in the presence of the radical trap 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO), which resulted in measured disappearance quantum yields of Φ = 0.037 ± 0.003 for (COD)PtMe2 and Φ = 0.44 ± 0.02 for (COD)PtMeCl at 334 nm. Weak luminescence was observed for 1a and 1b, and it was determined that emissive decay is not competitive with Pt-CH3 bond homolysis. DFT studies enabled assignment of both SBLCT and MLCT transitions in the UV/vis spectra of 1a, while 1b only exhibits MLCT transitions. These effects can be attributed to the symmetry of the mol. and its electronic structure.

From this literature《Photochemistry of 1,5-Cyclooctadiene Platinum Complexes for Photoassisted Chemical Vapor Deposition》,we know some information about this compound(12080-32-9)Related Products of 12080-32-9, but this is not all information, there are many literatures related to this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Name: Dichloro(1,5-cyclooctadiene)platinum(II). The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about C-C* Platinum(II) Complexes with PtXPX Metallacycle Forming (X = N and S) Auxiliary Ligands: Synthesis, Crystal Structures, and Properties. Author is Stipurin, Sergej; Wurl, Felix; Strassner, Thomas.

The synthesis of cyclometalated NHC Pt(II) complexes with two types of P-containing ligands is reported. Different synthetic approaches were used for each compound class. Dithiophosphinate and iminophosphonamide ligands form four-membered PtXPX metallacycles with coordination by either S or N atoms (= X). The complexes are fully characterized, including two solid-state structures. Addnl., the photophys. and electrochem. properties were examined, and the results are rationalized by d. functional theory calculations

From this literature《C-C* Platinum(II) Complexes with PtXPX Metallacycle Forming (X = N and S) Auxiliary Ligands: Synthesis, Crystal Structures, and Properties》,we know some information about this compound(12080-32-9)Name: Dichloro(1,5-cyclooctadiene)platinum(II), but this is not all information, there are many literatures related to this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Application In Synthesis of Dichloro(1,5-cyclooctadiene)platinum(II). Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Thermodynamics of adsorption of carbon dioxide on different metal oxides at temperatures from 313 to 353 K and pressures up to 25 MPa. Author is Crone, Marlene; Tuerk, Michael.

This paper presents adsorption isotherm data of CO2 on four different metal oxides. Absolute adsorption isotherms of CO2 at 313 K on WO3 and at T = 313 K, 333 K, 353 K on CeO2, TiO2 and Al2O3 and pressures up to p = 25 MPa were determined from CO2 excess adsorption isotherms. It was found at 313 K a maximum absolute loading of 0.3 mmol g-1 for WO3, of 1.7 mmol g-1 for CeO2, of 3.1 mmol g-1 for TiO2 and of 6.3 mmol g-1 for Al2O3. All adsorption isotherms were fitted to the Freundlich, Langmuir, Pade, Sips and Toth models and the Pade model present a better fitting than the other models. Based on these data, the Pade and the Langmuir model were used to determine the isosteric enthalpy of adsorption which was found to be dependent on the loading and the used model.

From this literature《Thermodynamics of adsorption of carbon dioxide on different metal oxides at temperatures from 313 to 353 K and pressures up to 25 MPa》,we know some information about this compound(12080-32-9)Application In Synthesis of Dichloro(1,5-cyclooctadiene)platinum(II), but this is not all information, there are many literatures related to this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 12080-32-9, is researched, Molecular C8H12Cl2Pt, about The importance of intramolecular conductivity in three dimensional molecular solids, the main research direction is macrocyclic semiconductor preparation crystal structure electron mobility conductivity.Computed Properties of C8H12Cl2Pt.

Recent years have seen tremendous progress towards understanding the relation between the mol. structure and function of organic field effect transistors. The metrics for organic field effect transistors, which are characterized by mobility and the on/off ratio, are known to be enhanced when the intermol. interaction is strong and the intramol. reorganization energy is low. While these requirements are adequate when describing organic field effect transistors with simple and planar aromatic mol. components, they are insufficient for complex building blocks, which have the potential to localize a carrier on the mol. Here, we show that intramol. conductivity can play a role in controlling device characteristics of organic field effect transistors made with macrocycle building blocks. We use two isomeric macrocyclic semiconductors that consist of perylene diimides linked with bithiophenes and find that the trans-linked macrocycle has a higher mobility than the cis-based device. Through a combination of single mol. junction conductance measurements of the components of the macrocycles, control experiments with acyclic counterparts to the macrocycles, and analyses of each of the materials using spectroscopy, electrochem., and d. functional theory, we attribute the difference in electron mobility of the OFETs created with the two isomers to the difference in intramol. conductivity of the two macrocycles.

From this literature《The importance of intramolecular conductivity in three dimensional molecular solids》,we know some information about this compound(12080-32-9)Computed Properties of C8H12Cl2Pt, but this is not all information, there are many literatures related to this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Electric Literature of C8H12Cl2Pt. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Platinum(II) Complexes with Bis(pyrazolyl)borate Ligands: Increased Molecular Rigidity for Bidentate Ligand Systems. Author is Soellner, Johannes; Pinter, Piermaria; Stipurin, Sergej; Strassner, Thomas.

The structural motif of platinum(II) complexes bearing cyclometalating N-heterocyclic carbene ligands can be used to design deep-blue phosphors for application in organic light-emitting diodes. However, the photophys. properties of the resulting mols. are also highly dependent on the auxiliary ligand. These often allow mol. deformations in the excited state which contribute to non-radiative decay processes that diminish the attainable quantum yield. The use of bis(pyrazolyl)borate-based auxiliary ligands enforces a high mol. rigidity due to their unique geometry. The steric crowding in the coordination sphere inhibits deformation processes and results in highly efficient deep-blue platinum(II) emitters with CIE coordinates below (0.15; 0.15).

From this literature《Platinum(II) Complexes with Bis(pyrazolyl)borate Ligands: Increased Molecular Rigidity for Bidentate Ligand Systems》,we know some information about this compound(12080-32-9)Electric Literature of C8H12Cl2Pt, but this is not all information, there are many literatures related to this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Application of 12080-32-9. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Multifunctional Pt(II)-Based Metallo-Supramolecular Polymer with Carboxylic Acid Groups: Electrochemical, Mechanochemical, Humidity, and pH Response. Author is Chakraborty, Chanchal; Rana, Utpal; Moriyama, Satoshi; Higuchi, Masayoshi.

We report multifunctional Pt(II)-based metallo-supramol. polymer with carboxylic acid groups (polyPtC). The polymer showed multi-stimuli-responsive emission to electrochem. redox, mech. force, humidity, and pH. It also exhibited humidity-responsive ionic conductivity Furthermore, it displayed electrofluorochromism. The emission switching between the two transition states (3MLCT/3LLCT and 3MMLCT) was based on the reversible changes of the interchain Pt-Pt interaction in polyPtC, which was caused by the secondary interaction or the crystalline-amorphous transition. The ionic conductivity of polyPtC was responsible for the humidity and the real-time humidity sensor with the polymer film was demonstrated on interdigitated Pt-electrodes. A solid-state electrochromic device with the polymer film was successfully fabricated to show reversible yellow-to-black electrochromism. In addition, it was revealed by the electrofluorochromic study that the pristine 3MLCT/3LLCT emission was quenched in the electrochem. reduced state (the black state), because the radical anion species of the ligand (tpy·-) generated at the neg. potential caused the repulsion among the polymer chains, expanded the Pt-Pt distance, and prevented the emission.

From this literature《Multifunctional Pt(II)-Based Metallo-Supramolecular Polymer with Carboxylic Acid Groups: Electrochemical, Mechanochemical, Humidity, and pH Response》,we know some information about this compound(12080-32-9)Application of 12080-32-9, but this is not all information, there are many literatures related to this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Boi, Filippo S.; Wang, Jiayu; He, Yi; Wen, Jiqiu; Wang, Shanling; Zhang, Xi; Yu, Tian; Shi, Lin; Ma, Qiuyan; Lan, Mu; Lei, Li; Xiang, Gang published the article 《Encapsulation of FePt and FePt3 alloys inside carbon-foam materials》. Keywords: iron platinum alloy encapsulation carbon foam surface structure magnetization.They researched the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ).Computed Properties of C8H12Cl2Pt. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:12080-32-9) here.

We demonstrate an advanced chem. vapor deposition (CVD) approach in which the addition of Pt-containing hydrocarbons to ferrocene allows the nucleation of a novel carbon-foam material completely filled with elemental Fe and Pt crystal-phases. These phases are then found to alloy into tetragonal FePt and cubic FePt3 in specific annealing conditions. A dependence of the FePt nucleation on the Ar/H2 flow rate is reported. In addition, high pressure (5 GPa) experiments are found to favor the formation of a single FePt3 encapsulated phase together with the nucleation of C-O rich carbon layers in the foam surface.

From this literature《Encapsulation of FePt and FePt3 alloys inside carbon-foam materials》,we know some information about this compound(12080-32-9)Computed Properties of C8H12Cl2Pt, but this is not all information, there are many literatures related to this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Angewandte Chemie, International Edition called [n]-Cyclo-9,9-dibutyl-2,7-fluorene (n=4, 5): Nanoring Size Influence in Carbon-Bridged Cyclo-para-phenylenes, Author is Sicard, Lambert; Lucas, Fabien; Jeannin, Olivier; Bouit, Pierre-Antoine; Rault-Berthelot, Joelle; Quinton, Cassandre; Poriel, Cyril, which mentions a compound: 12080-32-9, SMILESS is C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-], Molecular C8H12Cl2Pt, Related Products of 12080-32-9.

For the last ten years, ring-shaped π-conjugated macrocycles possessing radially directed π-orbitals have been subject to intense research. The electronic properties of these rings are deeply dependent on their size. However, most studies involve the flagship family of nanorings: the cyclo-para-phenylenes. We report herein the synthesis and study of the first examples of cyclofluorenes possessing five constituting fluorene units. The structural, optical and electrochem. properties were elucidated by X-ray crystallog., UV-vis absorption and fluorescence spectroscopy, and cyclic voltammetry. By comparison with a shorter analog, we show how the electronic properties of [5]-cyclofluorenes are drastically different from those of [4]-cyclofluorenes, highlighting the key role played by the ring size in the cyclofluorene family.

From this literature《[n]-Cyclo-9,9-dibutyl-2,7-fluorene (n=4, 5): Nanoring Size Influence in Carbon-Bridged Cyclo-para-phenylenes》,we know some information about this compound(12080-32-9)Related Products of 12080-32-9, but this is not all information, there are many literatures related to this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Mandapati, Pavan; Braun, Jason D.; Killeen, Charles; Davis, Rebecca L.; Williams, J. A. Gareth; Herbert, David E. published the article 《Luminescent Platinum(II) Complexes of N^N-^N Amido Ligands with Benzannulated N-Heterocyclic Donor Arms: Quinolines Offer Unexpectedly Deeper Red Phosphorescence than Phenanthridines》. Keywords: platinum chloride benzannulated amido ligand complex preparation phosphorescence; thermal stability DFT platinum chloride benzannulated amido ligand; crystal structure platinum chloride benzannulated amido ligand.They researched the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ).Category: alcohols-buliding-blocks. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:12080-32-9) here.

A platform for investigating the impact of π-extension in benzannulated, anionic pincer-type N^N-^N-coordinating amido ligands and their Pt(II) complexes is presented. Based on bis(8-quinolinyl)amine, sym. and asym. proligands bearing quinoline or π-extended phenanthridine (3,4-benzoquinoline) units are reported, along with their red-emitting, phosphorescent Pt(II) complexes of the form (N^N-^N)PtCl. Comparing the photophys. properties of complexes of (quinolinyl)amido ligands with those of π-extended (phenanthridinyl)amido analogs revealed a counterintuitive impact of site-selective benzannulation. Contrary to conventional assumptions regarding π-extension, and in contrast to isoenergetic lowest energy absorption bands and a red shift in fluorescence from the organic proligands, a blue shift of nearly 40 nm in the emission wavelength is observed for Pt(II) complexes with more extended bis(phenanthridinyl) ligand π-systems. Comparing the ground state and triplet excited state structures optimized from d. functional theory (DFT) and time-dependent-DFT calculations, we trace this effect to a greater rigidity of the benzannulated complexes, resulting in a higher energy emissive triplet state, rather than to a significant perturbation of orbital energies caused by π-extension. A counterintuitive impact of π-extension on luminescence from deep red emitting Pt(II) complexes of benzannulated, anionic pincer-type N^N-^N-coordinating amido ligands is reported. Contrary to conventional assumptions, isoenergetic lowest energy absorption bands and a red shift in fluorescence from the organic proligands, a blue shift in the emission wavelength is observed for Pt(II) complexes with more extended bis(phenanthridinyl) π-systems, traced to a greater rigidity of the benzannulated complexes and a higher energy triplet state.

When you point to this article, it is believed that you are also very interested in this compound(12080-32-9)Category: alcohols-buliding-blocks and due to space limitations, I can only present the most important information.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts