Category: 12080-32-9

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Flexible Platinum(0) Coordination to a Ditungsten Ethanediylidyne, published in 2019, which mentions a compound: 12080-32-9, mainly applied to crystal structure platinum coordinate ditungsten ethanediylidyne complex; mol structure platinum coordinate ditungsten ethanediylidyne complex; platinum NMR coordinate ditungsten ethanediylidyne complex; bis(carbyne)s; carbido ligands; carbynes; dicarbido ligands; polymetallic compounds, Category: alcohols-buliding-blocks.

The lithiocarbyne [W(CLi)(CO)2(Tp*)] (Tp*=hydrotris(3,5-dimethylpyrazol-1-yl)borate) reacts with [PtCl2(L2)] (L2 = 1,5-cyclo-octadiene, norbornadiene) to furnish ditungsten ethanediylidyne complexes, [W2{μ-C2Pt(L2)}(CO)4(Tp*)2], wherein a trigonal platinum(0) center unsym. ligates one W C bond in the solid state but rapidly shimmies between the two W C bonds in solution The η4-dienes are displaced by monodentate CO or isocyanide ligands to provide derivatives where both W C bonds coordinate to a single Pt0 center, attended by significant distortion of the WCCW spine.

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Safety of Dichloro(1,5-cyclooctadiene)platinum(II). Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Roles played by carbene substituents during ligand transfer reactions between tungsten fischer carbene complexes and [Pt(COD)Cl2]. Author is Weststrate, Nora-ann; Hassenruck, Christopher; Liles, David C.; Lotz, Simon; Gorls, Helmar; Winter, Rainer F..

Fischer carbene ligand transfer reactions from [W{C(X)(C6H4-4-R)}(CO)5] (X = OEt: a series; X = NMe2: b series), containing remote tertiary amino substituents R = R’2N at the Ph ring, to Pt(II) of [Pt(COD)Cl2] precursors, were studied. The number of carbene ligands transferred per Pt ion in these cases are determined by the electronic and steric properties of the heteroatoms of the carbene ligand. Thus, neutral bis(carbene) complexes, [Pt{C(X)(C6H4-4-R)}2Cl2], (R = H (1a); R = NR’2 and R’ = Me (2a), Ph (3a), or 4-BrC6H4 (4a)), are formed from the ethoxycarbene precursors (X = OEt), while cationic tris(carbene) complexes [Pt{C(X)(C6H4-4-R)}3Cl]+ Z-, (R = H (1b) and R = NR’2 and R’ = Me (2b), Ph (3b), or 4-BrC6H4 (4b)) were obtained from the aminocarbene precursors (X = NMe2), the latter with different counterions Z- = Cl-, [W(CO)5Cl]- or PF-6. Electro- and spectroelectrochem. studies indicate consecutive oxidations of the individual carbene ligands, but also a lack of electronic interactions across the (X)C:Pt:C(X) linkages.

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Formula: C8H12Cl2Pt. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Ditopic dithiocarbamate ligands for the production of trinuclear species. Author is Marin-Carrillo, Edgar; Ruiz-Martinez, Adrian; Valdes, Hugo; Reyes-Martinez, Reyna; Hernandez-Ortega, Simon; Adriana Aguilar-Castillo, Bethsy; Morales-Morales, David.

Reactions of group 10 transition metals with the ditopic ligand dipicolyldithiocarbamate (DPDTC) were performed. Thus, 1:2 reactions of [Ni(CH3COO)2], [Pd(COD)Cl2] or [Pt(COD)Cl2] with DPDTC produced monomeric complexes of the type [M(κ2-SCS-DPDTC)2, M = Ni (1), Pd (2) or Pt (3)] with the dithiocarbamate ligand (DTC) coordinated in a typical chelate κ2-SCS fashion. Interestingly, the reaction of [NiCl2] with DPDTC, under similar conditions, afforded the organic compound 2-(pyridin-2-ylmethyl)imidazo[1,5-a]pyri-dine-3(2 H)-thione (4) as unique product. In order to prove the ditopic nature of the ligand DPDTC, complex [Pd(κ2-SCS-DPDTC)2] (2) was further reacted with [ZnCl2] in a 1:2 M ratio to yield the trinuclear complex [Cl2Zn(κ2-NN-DPDTC-SCS-κ2)Pd(κ2-SCS-DPDTC-NN-κ2)ZnCl2] (5). The mol. structures of all compounds were determinate by typical anal. techniques including the unequivocal determination of all structures by single crystal x-ray diffraction anal. As expected, complexes 1-3 are isostructural, and the metal centers exhibiting slightly distorted square-planar geometries. While in 5, the trinuclear nature of the complex in confirmed exhibiting a nice combination of tetrahedral-square planar-tetrahedral geometries for the Zn-Pd-Zn centers resp.

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Related Products of 12080-32-9. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Bidentate Disilicate Framework for Bis-Grafted Surface Species.

Recent advances in surface organometallic chem. have enabled the detailed characterization of the surface species in single-site heterogeneous catalysts. However, the selective formation of bis-grafted surface species remains challenging because of the heterogeneity of the supporting surface. Herein, the authors introduce a metal complex bearing bidentate disilicate ligands, -OSi(OtBu)2OSi(OtBu)2O-, as a mol. precursor, which has a silicate framework adjacent to the metal (Pt) center. The grafting of the precursors on SiO2 supports (MCM-41 and CARiACT Q10) proceeded through a substitution reaction on the Si atoms of the disilicate ligand, which was verified by the detection of isobutene and tBuOH as the elimination products, to selectively yield bis-grafted surface species. The chem. structure of the surface species was characterized by solid-state NMR, and the chem. shift values of the ancillary ligands and 195Pt nuclei suggested that the bidentate coordination sphere was maintained following grafting.

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Safety of Dichloro(1,5-cyclooctadiene)platinum(II). The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Bidentate Disilicate Framework for Bis-Grafted Surface Species. Author is Ishizaka, Yusuke; Arai, Natsumi; Matsumoto, Kazuhiro; Nagashima, Hiroki; Takeuchi, Katsuhiko; Fukaya, Norihisa; Yasuda, Hiroyuki; Sato, Kazuhiko; Choi, Jun-Chul.

Recent advances in surface organometallic chem. have enabled the detailed characterization of the surface species in single-site heterogeneous catalysts. However, the selective formation of bis-grafted surface species remains challenging because of the heterogeneity of the supporting surface. Herein, the authors introduce a metal complex bearing bidentate disilicate ligands, -OSi(OtBu)2OSi(OtBu)2O-, as a mol. precursor, which has a silicate framework adjacent to the metal (Pt) center. The grafting of the precursors on SiO2 supports (MCM-41 and CARiACT Q10) proceeded through a substitution reaction on the Si atoms of the disilicate ligand, which was verified by the detection of isobutene and tBuOH as the elimination products, to selectively yield bis-grafted surface species. The chem. structure of the surface species was characterized by solid-state NMR, and the chem. shift values of the ancillary ligands and 195Pt nuclei suggested that the bidentate coordination sphere was maintained following grafting.

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So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Barker, Nathaniel M.; Taylor, Stephen D.; Ferguson, Ethan; Krause, Jeanette A.; Oliver, Allen G.; Connick, William B.; Zhang, Peng researched the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ).Synthetic Route of C8H12Cl2Pt.They published the article 《Water’s Role in Polymorphic Platinum(II) Complexes》 about this compound( cas:12080-32-9 ) in Inorganic Chemistry. Keywords: platinum terpyridine complex preparation vapochromism fluorescence; optimized mol structure platinum terpyridine complex; crystal structure platinum terpyridine complex. We’ll tell you more about this compound (cas:12080-32-9).

Solvent plays a vital role in the recrystallization process and resulting crystallinity of materials. This role is of such importance that it can control the stability and utility of materials. In this work, the inclusion of a solvent in the crystalline lattice, specifically water, drastically affects the overall stability of two platinum polymorphs. [Pt(tpy)Cl]BF4 (tpy = 2,2′;6’2”-terpyridine) crystallizes in three forms, red (1R) and blue (1B) polymorphs and a yellow nonsolvated form (2). 1R is the more stable of the two polymorphs, whereas 1B loses crystallinity upon dehydration at ambient conditions resulting in the formation of 2. Close examination of the solid-state extended structures of the two polymorphs reveals that 1R has a lattice arrangement that is more conducive to stronger intermol. interactions compared to 1B, thereby promoting greater stability. In addition, these two polymorphs exhibit unique vapochromic responses when exposed to various solvents.

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Name: Dichloro(1,5-cyclooctadiene)platinum(II). The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Transition metal decorated soft nanomaterials through modular self-assembly of an asymmetric hybrid polyoxometalate. Author is Hampson, Elizabeth; Cameron, Jamie M.; Watts, Julie A.; Newton, Graham N..

An asym. functionalised Wells-Dawson organic-inorganic hybrid polyoxometalate has been post-functionalised by Pt2+ coordination, and demonstrates self-assembly into surface-decorated micellar nanostructures. This multifunctional hybrid material is found to be a redox-active soft nanomaterial and demonstrates a new mol. design strategy with potential for applications in photo- or electro-catalysis.

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Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Inorganic Chemistry called Luminescent Platinum(II) Complexes of N^N-^N Amido Ligands with Benzannulated N-Heterocyclic Donor Arms: Quinolines Offer Unexpectedly Deeper Red Phosphorescence than Phenanthridines, Author is Mandapati, Pavan; Braun, Jason D.; Killeen, Charles; Davis, Rebecca L.; Williams, J. A. Gareth; Herbert, David E., which mentions a compound: 12080-32-9, SMILESS is C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-], Molecular C8H12Cl2Pt, Application of 12080-32-9.

A platform for investigating the impact of π-extension in benzannulated, anionic pincer-type N^N-^N-coordinating amido ligands and their Pt(II) complexes is presented. Based on bis(8-quinolinyl)amine, sym. and asym. proligands bearing quinoline or π-extended phenanthridine (3,4-benzoquinoline) units are reported, along with their red-emitting, phosphorescent Pt(II) complexes of the form (N^N-^N)PtCl. Comparing the photophys. properties of complexes of (quinolinyl)amido ligands with those of π-extended (phenanthridinyl)amido analogs revealed a counterintuitive impact of site-selective benzannulation. Contrary to conventional assumptions regarding π-extension, and in contrast to isoenergetic lowest energy absorption bands and a red shift in fluorescence from the organic proligands, a blue shift of nearly 40 nm in the emission wavelength is observed for Pt(II) complexes with more extended bis(phenanthridinyl) ligand π-systems. Comparing the ground state and triplet excited state structures optimized from d. functional theory (DFT) and time-dependent-DFT calculations, we trace this effect to a greater rigidity of the benzannulated complexes, resulting in a higher energy emissive triplet state, rather than to a significant perturbation of orbital energies caused by π-extension. A counterintuitive impact of π-extension on luminescence from deep red emitting Pt(II) complexes of benzannulated, anionic pincer-type N^N-^N-coordinating amido ligands is reported. Contrary to conventional assumptions, isoenergetic lowest energy absorption bands and a red shift in fluorescence from the organic proligands, a blue shift in the emission wavelength is observed for Pt(II) complexes with more extended bis(phenanthridinyl) π-systems, traced to a greater rigidity of the benzannulated complexes and a higher energy triplet state.

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Related Products of 12080-32-9. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Heterobimetallic PtII-AgI complex supported by diphenyl(2-pyrimidyl)phosphine: Synthesis and thermochromic photoluminescence. Author is Artem’ev, Alexander V.; Rogovoy, Maxim I.; Samsonenko, Denis G.; Rakhmanova, Mariana I..

The reaction of diphenyl(2-pyrimidyl)phosphine (L) derived complex [Pt(L)2Cl2] with AgNO3 (1:3 M ratio, resp.) results in assembly of heterobimetallic complex [AgPt(L)2(NO3)3], wherein Pt → Ag dative bond of 2.9088(2) Å is formed. This complex features thermochromic photoluminescence that appears as ∼40 nm red shift of an emission maximum upon cooling from 300 to 77 K. The related PdII/AgI complex, [AgPd(L)2(NO3)3], showing Pd → Ag dative bond of 2.9098(5) Å, also was synthesized and structurally attested.

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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 12080-32-9, is researched, Molecular C8H12Cl2Pt, about Photophysical Properties of Phosphorescent Mono- and Bimetallic Platinum(II) Complexes with C C* Cyclometalating NHC Ligands, the main research direction is imidazopyridinyl bimetallic platinum pyrazolate complex preparation electronic structure phosphorescence; crystal structure imidazopyridine bimetallic platinum pyrazolate complex; mol structure imidazopyridine bimetallic platinum pyrazolate complex; imidazopyridine cyclometalation platinum complex.Recommanded Product: 12080-32-9.

Due to their square-planar geometry, Pt(II) complexes demonstrate an extraordinary and unique photophys. behavior. The photophys. properties of monometallic Pt(II) complexes depend on the concentration, while in bimetallic Pt(II) complexes they depend on the distance between the metal centers. The authors reveal a correlation between the electronic and photophys. properties of monomeric monometallic Pt(II) complexes and their aggregates with the corresponding bimetallic complexes.

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