Tag: M.W=100-150

Quality Control of (4-Methoxyphenyl)methanol. Authors Wu, SP; Zhang, H; Cao, QE; Zhao, QH; Fang, WH in ROYAL SOC CHEMISTRY published article about in [Wu, Shipeng; Zhang, Hao; Cao, Qiue; Zhao, Qihua; Fang, Wenhao] Yunnan Univ, Sch Chem Sci & Technol, Key Lab Med Chem Nat Resource, Minist Educ,Funct Mol Anal & Biotransformat Key L, 2 North Cuihu Rd, Kunming 650091, Yunnan, Peoples R China; [Cao, Qiue; Fang, Wenhao] Yunnan Univ, Natl Demonstrat Ctr Expt Chem & Chem Engn Educ, Kunming 650091, Yunnan, Peoples R China in 2021, Cited 46. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Direct oxidative coupling of alcohols with amines using a non-precious metal oxide catalyst under mild conditions is highly desirable for imine synthesis. In this work, a mesoporous Mn1ZrxOy solid solution catalyst prepared by a co-precipitation method showed excellent catalytic performance in imine synthesis from primary alcohols and amines without base additives in an air atmosphere. XRD, N-2 physisorption, H-2-TPR, O-2-TPD, EPR and XPS were comprehensively used to unravel its structural, redox and amphoteric properties that closely depended on the interaction between MnOy and ZrO2 with a variable Zr ratio. The Mn1Zr0.5Oy catalyst presented the highest fractions of Mn3+ ions and reactive oxygen species on the surface, and the highest concentrations of acidic-basic sites, which were disclosed to play important roles in activating alcohols and molecular O-2 in the rate-determining step. In the model reaction of oxidative coupling of benzyl alcohol with aniline, such enhanced features of the Mn1Zr0.5Oy catalyst can promote the intrinsic catalytic activity (iTOF of 1.87 h(-1)) and boost benzylideneaniline formation (5.56 mmol g(cat).(-1) h(-1)) based on a >99% yield at 80 degrees C respectively at a fast response. It can also work effectively at a room temperature of 30 degrees C, as well as for the gram-grade synthesis. This is one of the best results among all the MnOy-based catalysts in the literature. Moreover, this catalyst showed good stability and a wide substrate scope with good to excellent yields of imines.

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Authors Shen, YM; Xue, Y; Yan, M; Mao, HL; Cheng, H; Chen, Z; Sui, ZW; Zhu, SB; Yu, XJ; Zhuang, JL in ROYAL SOC CHEMISTRY published article about CONJUGATED MICROPOROUS POLYMERS; AEROBIC OXIDATION; ORGANIC FRAMEWORKS; CATALYTIC-SYSTEM; SUPPORTED TEMPO; CORE-SHELL; SPHERES; DESIGN in [Shen, Yan-Ming; Xue, Yun; Yan, Mi; Mao, Hui-Ling; Cheng, Hu; Chen, Zhuo; Yu, Xiu-Jun; Zhuang, Jin-Liang] Guizhou Normal Univ, Key Lab Funct Mat Chem Guizhou Prov, Sch Chem & Mat Sci, 116 Baoshan Rd North, Guiyang 550001, Peoples R China; [Sui, Zhi-Wei] Natl Inst Metrol, Ctr Adv Measurement Sci, Beijing, Peoples R China; [Zhu, Shao-Bin; Zhuang, Jin-Liang] NanoFCM INC, Xiamen Pioneering Pk Overseas Chinese Scholars, Xiamen 361005, Peoples R China; [Yu, Xiu-Jun] Goethe Univ Frankfurt, Inst Inorgan & Analyt Chem, Max von Laue Str 7, D-60438 Frankfurt, Germany in 2021, Cited 34. Computed Properties of C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A bottom-up approach was developed to prepare TEMPO radical decorated hollow aromatic frameworks (HPAF-TEMPO) by using TEMPO radical functionalized monomers and SiO2 nanospheres as templates. The accessible inner layer, high density of TEMPO sites, and hybrid micro-/mesopores of the HPAF-TEMPO enable the aerobic oxidation of a broad range of alcohols with high efficiency and excellent selectivity.

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In 2021 RSC ADV published article about N-PROPYLAMMONIUM PERRUTHENATE; ALCOHOLS in [Mirbagheri, Reza; Elhamifar, Dawood; Hajati, Shaaker] Univ Yasuj, Dept Chem, Yasuj 7591874831, Iran; [Hajati, Shaaker] Mat & Energy Res Ctr MERC, Dept Semicond, POB 31787-316, Tehran, Iran in 2021, Cited 91. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Category: alcohols-buliding-blocks

A novel method was used to prepare a magnetic phenylene-based periodic mesoporous organosilica nanocomposite with yolk-shell structure (Fe3O4@YSPMO). The Fe3O4@YSPMO nanomaterial was prepared by using easily accessible pluronic-P123 and cetyltrimethylammonium bromide (CTAB) surfactants under basic conditions. This material was employed for effective immobilization of potassium perruthenate to prepare an Fe3O4@YSPMO@Ru nanocatalyst for the aerobic oxidation of alcohols. The physiochemical properties of the designed Fe3O4@YSPMO@Ru nanocomposite were studied using PXRD, FT-IR, TGA, SEM, TEM, ICP, VSM and XPS analyses. Fe3O4@YSPMO@Ru was effectively employed as a highly recoverable nanocatalyst in the selective aerobic oxidation of alcohols.

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An article Cross beta-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles WOS:000627441700007 published article about N,N-DIMETHYLFORMAMIDE-STABILIZED PALLADIUM NANOCLUSTERS; ALPHA-ALKYLATION; BORROWING HYDROGEN; GUERBET REACTION; N-BUTANOL; METHYLATION; KETONES; METHANOL; DIMETHYLFORMAMIDE; ALPHA,OMEGA-DIOLS in [Kobayashi, Masaki; Yamaguchi, Hiroki; Obora, Yasushi] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Suita, Osaka 5648680, Japan; [Suzuki, Takeyuki] Osaka Univ, Comprehens Anal Ctr, Inst Sci & Ind Res ISIR, 8-1 Mihogaoka, Ibaraki, Osaka 5670057, Japan in 2021, Cited 64. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. SDS of cas: 105-13-5

A simple method for the cross beta-alkylation of linear alcohols with benzyl alcohols in the presence of DMF-stabilized iridium nanoparticles was developed. The nanoparticles were prepared in one-step and thoroughly characterized. Furthermore, the optimum reaction conditions have a wide substrate scope and excellent product selectivity.

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I found the field of Chemistry very interesting. Saw the article Nickel-Copper bimetallic mesoporous nanoparticles: As an efficient heterogeneous catalyst for N-alkylation of amines with alcohols published in 2021. Computed Properties of C8H10O2, Reprint Addresses Kassaee, MZ (corresponding author), Tarbiat Modares Univ, Dept Chem, POB 14155-175, Tehran, Iran.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A bimetallic catalyst (Ni/Cu-MCM-41) is prepared via co-condensation method. The latter is characterized by Fourier transform infrared (FT-IR), X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), diffuse reflectance spectroscopy (DRS), and nitrogen adsorption-desorption analysis. Catalytic performance of Ni/Cu-MCM-41 is probed in N-alkylation of amines with alcohols through a hydrogen autotransfer process. Noteworthy, this catalytic system appears very efficient for synthesis of a range of secondary and tertiary amines in good to excellent isolated yields. Moreover, the catalyst is successfully recovered and reused four times without notable decrease in its activity.

Computed Properties of C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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I found the field of Chemistry very interesting. Saw the article Synthesis, Characterisation, and Determination of Physical Properties of New Two-Protonic Acid Ionic Liquid and its Catalytic Application in the Esterification published in 2021. Quality Control of (4-Methoxyphenyl)methanol, Reprint Addresses Khaligh, NG (corresponding author), Univ Malaya, Inst Postgrad Studies, Nanotechnol & Catalysis Res Ctr, 3rd Floor,Block A, Kuala Lumpur 50603, Malaysia.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A new ionic liquid was synthesised, and its chemical structure was elucidated by FT-IR, 1D NMR, 2D NMR, and mass analyses. Some physical properties, thermal behaviour, and thermal stability of this ionic liquid were investigated. The formation of a two-protonic acid salt namely 4,4′-trimethylene-N,N’-dipiperidinium sulfate instead of 4,4′-trimethylene-N,N’-dipiperidinium hydrogensulfate was evidenced by NMR analyses. The catalytic activity of this ionic liquid was demonstrated in the esterification reaction of n-butanol and glacial acetic acid under different conditions. The desired acetate was obtained in 62-88% yield without using a Dean-Stark apparatus under optimal conditions of 10 mol-% of the ionic liquid, an alcohol to glacial acetic acid mole ratio of 1.3 : 1.0, a temperature of 75-100 degrees C, and a reaction time of 4 h. alpha-Tocopherol (alpha-TCP), a highly efficient form of vitamin E, was also treated with glacial acetic acid in the presence of the ionic liquid, and O-acetyl-alpha-tocopherol (Ac-TCP) was obtained in 88.4% yield. The separation of esters was conducted during workup without the utilisation of high-cost column chromatography. The residue and ionic liquid were used in subsequent runs after the extraction of desired products. The ionic liquid exhibited high catalytic activity even after five runs with no significant change in its chemical structure and catalytic efficiency.

Welcome to talk about 105-13-5, If you have any questions, you can contact Shahnavaz, Z; Zaharani, L; Khaligh, NG; Mihankhah, T; Johan, MR or send Email.. Quality Control of (4-Methoxyphenyl)methanol

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Authors Feng, XS; Huang, M in PERGAMON-ELSEVIER SCIENCE LTD published article about ONE-POT SYNTHESIS; SELECTIVE ALKYLATION; EFFICIENT; COMPLEX; ANILINES; SUBSTITUTION; OXIDATION; AMIDES in [Feng, Xinshu; Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Guangzhou 510006, Peoples R China in 2021, Cited 40. Safety of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A series of air-stable N-heterocyclic carbene (NHC) Ir(III) complexes (Ir1-6), bearing various combinations of chlorine, pyridine and NHC ligands, were assayed for the N-alkylation of amines with alcohols. It was found that Ir3, with two monodentate 1,3-bis-methyl-imidazolylidene (IMe) ligands, emerged as the most active complex. A large variety of amines and primary alcohols were efficiently converted into mono-N-alkylated amines in 53-96% yields. As a special highlight, for the challenging MeOH, selective N-monomethylation could be achieved using KOH as a base under an air atmosphere. Moreover, this catalytic system was successfully applied to the gram-scale synthesis of some valuable compounds. (C) 2021 Elsevier Ltd. All rights reserved.

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Recently I am researching about MESOPOROUS MOLECULAR-SIEVE; METAL-SUPPORT INTERACTION; SELECTIVE HYDROGENATION; UNSATURATED ALDEHYDES; CINNAMYL ALCOHOL; ACTIVATED CARBON; HIGHLY EFFICIENT; CINNAMALDEHYDE; RUTHENIUM; COMPLEXES, Saw an article supported by the C1 Gas Refinery Program [2018M3D3A1A01018006]; National Research Foundation of Korea (NRF) – Ministry of Science, ICT, and Future Planning, Republic of Korea [2020M3H7A1098259]. Published in ELSEVIER SCIENCE INC in NEW YORK ,Authors: Padmanaban, S; Lee, Y; Yoon, S. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. Safety of (4-Methoxyphenyl)methanol

Selective hydrogenation of the carbonyl functional group of alpha,beta-unsaturated carbonyl compounds affords industrially important allylic alcohols. However, achieving the selective reduction of the carbonyl group in the presence of the activated olefinic group is challenging. Therefore, the development of a highly chemoselective, efficient, and recyclable catalyst for this transformation is greatly desirable from the industrial and environmental viewpoints. In this study, a Ru-immobilized bisphosphine-based porous organic polymer (Ru@PP-POP) was used as an efficient heterogeneous catalyst for chemoselective hydrogenation of cinnamaldehyde (CAL) to cinnamyl alcohol with high chemoselectivity (98%) and excellent recyclability. To the best of our knowledge, the catalyst, Ru@PP-POP showed a high turnover number (970) and a high turnover frequency (240h(1)) which is the best activity obtained using a phosphine based heterogeneous Ru-catalyst in this transformation. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

Safety of (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Padmanaban, S; Lee, Y; Yoon, S or send Email.

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An article Electrochemical Arylation of Aldehydes, Ketones, and Alcohols: from Cathodic Reduction to Convergent Paired Electrolysis WOS:000621048400001 published article about C-H FUNCTIONALIZATION; PHOTOREDOX CATALYSIS; CARBONYL-COMPOUNDS; COUPLING REACTIONS; NICKEL CATALYSIS; GRIGNARD; HYDROGEN; HALIDES; IMINES; REAGENTS in [Zhang, Sheng; Li, Lijun; Li, Jingjing; Shi, Jianxue; Xu, Kun; Gao, Wenchao; Zong, Luyi] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Engn Technol Res Ctr Henan Prov Photo & Electroch, Nanyang, Peoples R China; [Li, Guigen; Findlater, Michael] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79423 USA in 2021, Cited 67. Safety of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Arylation of carbonyls, one of the most common approaches toward alcohols, has received tremendous attention, as alcohols are important feedstocks and building blocks in organic synthesis. Despite great progress, there is still a great gap to develop an ideal arylation method featuring mild conditions, good functional group tolerance, and readily available starting materials. We now show that electrochemical arylation can fill the gap. By taking advantage of synthetic electrochemistry, commercially available aldehydes (ketones) and benzylic alcohols can be readily arylated to provide a general and scalable access to structurally diverse alcohols (97 examples, >10 gram-scale). More importantly, convergent paired electrolysis, the ideal but challenging electrochemical technology, was employed to transform low-value alcohols into more useful alcohols. Detailed mechanism study suggests that two plausible pathways are involved in the redox neutral alpha-arylation of benzylic alcohols.

Welcome to talk about 105-13-5, If you have any questions, you can contact Zhang, S; Li, LJ; Li, JJ; Shi, JX; Xu, K; Gao, WC; Zong, LY; Li, GG; Findlater, M or send Email.. Safety of (4-Methoxyphenyl)methanol

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An article OH/Na co-functionalized carbon nitride: directional charge transfer and enhanced photocatalytic oxidation ability WOS:000509894100024 published article about FACILE SYNTHESIS; REACTANTS ACTIVATION; NO ADSORPTION; DOPED G-C3N4; EFFICIENT; NANOSHEETS; ZIRCONIA; REACTIVITY; VACANCIES; MECHANISM in [Wang, Jiadong; Chen, Ruimin; Yuan, Chaowei; Dong, Fan; Sun, Yanjuan] Chongqing Technol & Business Univ, Coll Environm & Resources, Chongqing Key Lab Catalysis & New Environm Mat, Chongqing 400067, Peoples R China; [Wang, Jiadong; Cui, Wen; He, Ye; Yuan, Chaowei; Sheng, Jianping; Li, Jieyuan; Dong, Fan; Sun, Yanjuan] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Res Ctr Environm Sci & Technol, Chengdu 611731, Peoples R China; [Cui, Wen] Southwest Petr Univ, Sch Mat Sci & Engn, Ctr New Energy Mat & Thchnol, Chengdu 610500, Peoples R China; [Zhan, Yuxin] Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400044, Peoples R China in 2020, Cited 60. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Product Details of 105-13-5

Graphitic carbon nitride (g-C3N4, CN for short) is a compelling visible-light responsive photocatalyst. However, its photocatalytic efficiency is low due to the random carrier transfer in planes and insufficient redox potential. Herein, we build oxygen functional group modified sodium-doped carbon nitride (OH/Na co-functionalized carbon nitride) to promote directional transfer of charge carriers for acceleration of separation and enhance redox potential for efficient oxidation of NO in air. Specifically, the function of sodium atoms could control the directional transfer of random carriers from the intralayer to the oxygen functional group-modified surface for the purpose of effectively reducing photogenerated electron-hole recombination. Meanwhile, the modification by oxygen-containing functional groups could adjust the band structure of CN, thereby increasing the oxidation-reduction potential of NO in the photocatalyst. The transformation pathways and reaction mechanism of photocatalytic NO oxidation on CN and OH/Na co-functionalized carbon nitride have also been explicated by ESR spectroscopy and in situ DRIFTS and compared. This work provides a new method for simultaneously controlling the random transfer of carriers and adjusting the energy band structure of CN to optimize its photocatalytic efficiency. It is also possible to extend this strategy to improve the performance of other 2D layered catalysts for photocatalytic oxidation.

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