Tag: M.W=100-150

An article Rapid, chemoselective and mild oxidation protocol for alcohols and ethers with recyclable N-chloro-N-(phenylsulfonyl)benzenesulfonamide WOS:000656983400003 published article about SELECTIVE OXIDATION; N-BROMOSUCCINIMIDE; SULFATED POLYBORATE; BENZYLIC ALCOHOLS; EFFICIENT; CATALYST; ALDEHYDES; COMPLEX; DERIVATIVES; WATER in [Palav, Amey; Misal, Balu; Ganwir, Prerna; Chaturbhuj, Ganesh] Inst Chem Technol, Mumbai 400019, Maharashtra, India; [Palav, Amey; Misal, Balu] Loba Chem Pvt Ltd, Res & Dev Ctr, Tarapur 401506, Thane, India; [Badani, Purav] Univ Mumbai, Dept Chem, Mumbai 400098, Maharashtra, India in 2021, Cited 42. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. HPLC of Formula: C8H10O2

Chlorine is the 20th most abundant element on the earth compared to bromine, iodine, and fluorine, a sulfonimide reagent, N-chloro-N-(phenylsulfonyl)benzenesulfonamide (NCBSI) was identified as a mild and selective oxidant. Without activation, the reagent was proved to oxidize primary and secondary alcohols as well as their symmetrical and mixed ethers to corresponding aldehydes and ketones. With recoverable PS-TEMPO catalyst, selective oxidation over chlorination of primary and secondary alcohols and their ethers with electron-donating substituents was achieved. The reagent precursor of NCBSI was recovered quantitatively and can be reused for synthesizing NCBSI. (C) 2021 Elsevier Ltd. All rights reserved.

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Recently I am researching about AROMATIC ALCOHOLS; MULTICOMPONENT SYNTHESIS; TIO2 NANOPARTICLES; AEROBIC OXIDATION; TITANIUM-DIOXIDE; IONIC LIQUIDS; METAL-OXIDES; EFFICIENT; ALDEHYDES; DEGRADATION, Saw an article supported by the Faculty of Chemistry of Semnan University. Quality Control of (4-Methoxyphenyl)methanol. Published in WILEY in HOBOKEN ,Authors: Taghavi, S; Amoozadeh, A; Nemati, F. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

BACKGROUND Deep eutectic solvents (DESs) are prepared by mixing solid organic precursors to form a liquid driven from strong hydrogen-bond interactions. The physical and chemical properties of these compounds have been widely investigated, and it has been shown that they are benign media for biotransformations, organicsynthesis, biodieselpreparation, and a sustainable media for nanoscale and functional materials. RESULTS This study is the first report on the synthesis of n-TiO2-P25@TDI@DES (urea: ZnCl2) with photo catalytic activity. This nano photocatalyst was obtained through covalent grafting of TiO2-P25 nanoparticles to an inexpensive and highly reactive linker (2,4-toluene diisocyanate). The presented nano photocatalyst has been employed as a covalently grafted Lewis acidic deep eutectic solvent to oxidize various primary benzyl alcohols to their corresponding carbonyl compounds by sodium nitrate as oxidant, under visible light exposure. CONCLUSION This highly efficient nanocatalyst was investigated by various characterization techniques including fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy (SEM with EDX), and elemental analysis. Owing to its enhanced catalytic activity, thermal stability, and environmentally friendly nature, the present method can be regarded as an attractive green chemistry approach. (c) 2020 Society of Chemical Industry (SCI)

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Quality Control of (4-Methoxyphenyl)methanol. Authors Sung, K; Lee, MH; Cheong, YJ; Kim, YK; Yu, S; Jang, HY in WILEY-V C H VERLAG GMBH published article about in [Sung, Kihyuk; Lee, Mi-hyun; Cheong, Yeon-Joo; Kim, Yu Kwon; Yu, Sungju; Jang, Hye-Young] Ajou Univ, Dept Energy Syst Res, Suwon 16499, South Korea in 2021, Cited 56. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Multi N-heterocyclic carbene(NHC)-modified iridium catalysts were employed in the beta-alkylation of alcohols; dimerization of primary alcohols (Guerbet reaction), cross-coupling of secondary and primary alcohols, and intramolecular cyclization of alcohols. Mechanistic studies of Guerbet reaction, including kinetic experiments, mass analysis, and density functional theory (DFT) calculation, were employed to explain the fast reaction promoted by bimetallic catalysts, and the dramatic reactivity increase of monometallic catalysts at the late stage of the reaction.

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SDS of cas: 105-13-5. Authors Yoshida, Y; Kukita, M; Omori, K; Mino, T; Sakamoto, M in ROYAL SOC CHEMISTRY published article about in [Yoshida, Yasushi; Kukita, Mayu; Omori, Kazuki; Mino, Takashi; Sakamoto, Masami] Chiha Univ, Grad Sch Engn, Mol Chiral Res Ctr, Inage Ku, 1-33 Yayoi Cho, Chiba, Chiba 2638522, Japan in 2021, Cited 96. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Umpolung reactions of imines, especially the asymmetric reactions, have been extensively studied as they provide access to important chiral amines in an efficient manner. The reactions studied range from simple Michael reactions to several kinds of other reactions such as the aza-benzoin reaction, aza-Stetter reaction, addition with MBH carbonate, and Ir-catalysed allylation. Herein, we report the first umpolung alkylation reaction of alpha-iminoesters with alkyl halides mediated by iminophosphorane as an organic superbase. The desired products were obtained in up to 82% yield with almost perfect regioselectivities. The key to the regioselectivity of this reaction was the use of 4-trifluoromethyl benzyl imines as a substrate. The products were successfully derivatised into the more functionalised molecules in good yields.

SDS of cas: 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Yoshida, Y; Kukita, M; Omori, K; Mino, T; Sakamoto, M or send Email.

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An article Reaction of Diisobutylaluminum Borohydride, a Binary Hydride, with Selected Organic Compounds Containing Representative Functional Groups WOS:000649101400016 published article about AROMATIC CARBOXYLIC-ACIDS; CATALYZED N-ALKYLATION; LITHIUM TRIETHYLBOROHYDRIDE; CORRESPONDING AMINES; REDUCING AGENTS; TERTIARY AMIDES; REDUCTION; NITRILES; ALCOHOLS; SECONDARY in [Amberchan, Gabriella; Snelling, Rachel A.; Moya, Enrique; Landi, Madison; Lutz, Kyle; Gatihi, Roxanne; Singaram, Bakthan] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA in 2021, Cited 84. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. HPLC of Formula: C8H10O2

The binary hydride, diisobutylaluminum borohydride [(iBu)(2)AlBH4], synthesized from diisobutylaluminum hydride (DIBAL) and borane dimethyl sulfide (BMS) has shown great potential in reducing a variety of organic functional groups. This unique binary hydride, (iBu)(2)AlBH4, is readily synthesized, versatile, and simple to use. Aldehydes, ketones, esters, and epoxides are reduced very fast to the corresponding alcohols in essentially quantitative yields. This binary hydride can reduce tertiary amides rapidly to the corresponding amines at 25 degrees C in an efficient manner. Furthermore, nitriles are converted into the corresponding amines in essentially quantitative yields. These reactions occur under ambient conditions and are completed in an hour or less. The reduction products are isolated through a simple acid-base extraction and without the use of column chromatography. Further investigation showed that (iBu)(2)AlBH4 has potential to be a selective hydride donor as shown through a series of competitive reactions. Similarities and differences between (iBu)(2)AlBH4, DIBAL, and BMS are discussed.

Welcome to talk about 105-13-5, If you have any questions, you can contact Amberchan, G; Snelling, RA; Moya, E; Landi, M; Lutz, K; Gatihi, R; Singaram, B or send Email.. HPLC of Formula: C8H10O2

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Authors Sato, K; Tanaka, S; Wang, JZ; Ishikawa, K; Tsuda, S; Narumi, T; Yoshiya, T; Mase, N in AMER CHEMICAL SOC published article about in [Sato, Kohei; Tanaka, Shoko] Shizuoka Univ, Grad Sch Sci & Technol, Hamamatsu, Shizuoka 4328561, Japan; [Wang, Junzhen; Ishikawa, Kenya] Shizuoka Univ, Dept Appl Chem & Biochem Engn, Fac Engn, Hamamatsu, Shizuoka 4328561, Japan; [Tsuda, Shugo; Yoshiya, Taku] Peptide Inst Inc, Ibaraki, Osaka 5670085, Japan; [Narumi, Tetsuo; Mase, Nobuyuki] Shizuoka Univ, Dept Appl Chem & Biochem Engn, Fac Engn,Grad Sch Sci & Technol, Course Appl Chem & Biochem Engn,Dept Engn,Grad Sc, Hamamatsu, Shizuoka 4328561, Japan; [Narumi, Tetsuo; Mase, Nobuyuki] Shizuoka Univ, Res Inst Green Sci & Technol, Hamamatsu, Shizuoka 4328561, Japan; [Sato, Kohei] Shizuoka Univ, Dept Appl Chem & Biochem Engn, Fac Engn, Course Appl Chem & Biochem Engn,Dept Engn,Grad Sc, Hamamatsu, Shizuoka 4328561, Japan in 2021, Cited 52. Recommanded Product: (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A novel late-stage solubilization of peptides using hydrazides is described. A solubilizing tag was attached through a selective N-alkylation at a hydrazide moiety with the aid of a 2-picoline-borane complex in 50% acetic acid-hexafluoro-2-propanol. The tag, which tolerates ligation and desulfurization conditions, can be detached by a Cu-mediated selective oxidative hydrolysis of the N-alkyl hydrazide. This new method was validated through the synthesis of HIV-1 protease.

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SDS of cas: 105-13-5. In 2021 ACS CATAL published article about PHOTOREDOX CATALYSIS; BOND FUNCTIONALIZATION; ACTIVATION; STRATEGY; TETRAHYDROISOQUINOLINES; ORGANOCATALYSIS; ALKYLATION; PHOTOLYSIS; CYANATION; RADICALS in [Kobayashi, Fumihisa; Fujita, Masashi; Ide, Takafumi; Ito, Yuta; Yamashita, Kenji; Egami, Hiromichi; Hamashima, Yoshitaka] Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, Shizuoka 4228526, Japan in 2021, Cited 70. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Thiobenzoic acid (TBA) can serve as a single-electron reducing agent under photoirradiation from a blue light-emitting diode, in the presence of appropriate electron acceptors, and the resulting sulfur-centered radical species undergoes hydrogen atom abstraction. This dual-role catalysis by TBA enables regioselectivie C alpha-H arylation of benzylamines, benzyl alcohols, and ethers, as well as dihydroimidazoles, with cyano(hetero)arenes in good yield, without the need for a transition-metal photocatalyst and/or synthetically elaborated organic dyes.

SDS of cas: 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Kobayashi, F; Fujita, M; Ide, T; Ito, Y; Yamashita, K; Egami, H; Hamashima, Y or send Email.

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Name: (4-Methoxyphenyl)methanol. Authors Yoshida, Y; Kukita, M; Omori, K; Mino, T; Sakamoto, M in ROYAL SOC CHEMISTRY published article about in [Yoshida, Yasushi; Kukita, Mayu; Omori, Kazuki; Mino, Takashi; Sakamoto, Masami] Chiha Univ, Grad Sch Engn, Mol Chiral Res Ctr, Inage Ku, 1-33 Yayoi Cho, Chiba, Chiba 2638522, Japan in 2021, Cited 96. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Umpolung reactions of imines, especially the asymmetric reactions, have been extensively studied as they provide access to important chiral amines in an efficient manner. The reactions studied range from simple Michael reactions to several kinds of other reactions such as the aza-benzoin reaction, aza-Stetter reaction, addition with MBH carbonate, and Ir-catalysed allylation. Herein, we report the first umpolung alkylation reaction of alpha-iminoesters with alkyl halides mediated by iminophosphorane as an organic superbase. The desired products were obtained in up to 82% yield with almost perfect regioselectivities. The key to the regioselectivity of this reaction was the use of 4-trifluoromethyl benzyl imines as a substrate. The products were successfully derivatised into the more functionalised molecules in good yields.

Name: (4-Methoxyphenyl)methanol. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Formula: C8H10O2. Authors Jeong, J; Fujita, K in AMER CHEMICAL SOC published article about in [Jeong, Jaeyoung; Fujita, Ken-ichi] Kyoto Univ, Grad Sch Human & Environm Studies, Kyoto 6068501, Japan in 2021, Cited 70. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A new catalytic system for N,N-dimethylamination of primary alcohols using aqueous dimethylamine in the absence of additional organic solvents has been developed. The reaction proceeds via borrowing hydrogen processes, which are atom-efficient and environmentally benign. An iridium catalyst bearing an N-heterocyclic carbene (NHC) ligand exhibited high performance, without showing any deactivation under aqueous conditions. In addition, valuable N,N-dimethylamine derivatives, including biologically active and pharmaceutical molecules, were synthesized. The practical application of this methodology was demonstrated by a gram-scale reaction.

Welcome to talk about 105-13-5, If you have any questions, you can contact Jeong, J; Fujita, K or send Email.. Formula: C8H10O2

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Formula: C8H10O2. Authors Sung, K; Lee, MH; Cheong, YJ; Kim, YK; Yu, S; Jang, HY in WILEY-V C H VERLAG GMBH published article about in [Sung, Kihyuk; Lee, Mi-hyun; Cheong, Yeon-Joo; Kim, Yu Kwon; Yu, Sungju; Jang, Hye-Young] Ajou Univ, Dept Energy Syst Res, Suwon 16499, South Korea in 2021, Cited 56. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Multi N-heterocyclic carbene(NHC)-modified iridium catalysts were employed in the beta-alkylation of alcohols; dimerization of primary alcohols (Guerbet reaction), cross-coupling of secondary and primary alcohols, and intramolecular cyclization of alcohols. Mechanistic studies of Guerbet reaction, including kinetic experiments, mass analysis, and density functional theory (DFT) calculation, were employed to explain the fast reaction promoted by bimetallic catalysts, and the dramatic reactivity increase of monometallic catalysts at the late stage of the reaction.

Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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